高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (4): 360.

• 研究简报 • 上一篇    下一篇

电子云伸展模型

陈忠厚   

  1. 四川师范学院化学系
  • 收稿日期:1983-11-29 出版日期:1985-04-24 发布日期:1985-04-24

The Nephelauxetic Model

Cben Zhongllou   

  1. Department of Chemistry, Sichuan Teachers College, Chengdu
  • Received:1983-11-29 Online:1985-04-24 Published:1985-04-24

摘要: 关于络离子中的价键,本文并不着眼于金属M与配体L之间是否交换电子,而是考虑自由离子波函数进入化学环境后将如何变化。鉴于自由离子与配位场理论中所用的静电排斥参量B、C以及旋-轨偶合参数ζα的定量计算只有在球对称场中才有意义,故有必要建立球对称场的分子轨道理论。

Abstract: In this paper the d radial function in ligand field has been expressed by adding the free-state d radial function with a empirical function. By using this model several crystalline electronic spectra of Cu2+ in environments of Cl- have been calculated and the results obtained are in good agreement with the experimental data.

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