高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (3): 244.

• 研究论文 • 上一篇    下一篇

投影解析法求直链烷烃内旋转时非键原子对间距离

张雪松   

  1. 吉林大学化学系
  • 收稿日期:1983-04-28 出版日期:1985-03-24 发布日期:1985-03-24

Calculation of the Non-Bonded Atom Pairs Distance in Straight Chain Paraffins with Analytical Projective Method

Zhang Xuesong   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1983-04-28 Online:1985-03-24 Published:1985-03-24

PDF (PC)

被引次数

1

摘要： 用旋转投影解析几何的方法,计算了链烃分子链上相邻原子上的非键原子对间的距离r(φi),及相间原子上的非键原子对间的距离r(φi,φ1+1.所得公式适用于链上不含双键的链状分子.

Abstract: The distance between non-bonded atom pairs have been calculated by use of analytical projective geometry method. The distance of non-bonded atom pairs attached to the adjacent molecular chain atoms, rab(φi), is given asThe distance between non-bonded atom pairs attached to the non-adjacent molecular chain atoms, ra b(φi,φi+1) is given asThe method suggested by the present author is simple but valid only for those chain molecules without double bonds.

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