(μ-苯硫)(μ-烃硫)六碳基二铁络合物的合成及波谱研究

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (2): 135.

(μ-苯硫)(μ-烃硫)六碳基二铁络合物的合成及波谱研究

宋礼成, 胡青眉, 刘向阳, 王积涛

南开大学化学系

收稿日期:1983-08-28 出版日期:1985-02-24 发布日期:1985-02-24

Synthesis and Spectral Studies of (μ-Phenylthio)(μ-Alkylthio) Hexacarbonyldiiron Complexes

Song Licheng, Hu Qingmei, Liu Xiangyang, Wang Jitao

Department of Chemistry, Xankai University, Tianjin

Received:1983-08-28 Online:1985-02-24 Published:1985-02-24

摘要/Abstract

摘要： 本文合成了(μ-PhS)(μ-RS)Fe₂(CO)₆系列的九个铁硫原子簇络合物,考察并确定了RX的结构对亲核取代反应活性的影响及络合物可能的空间异构体和比例.对由C≡O各向异性效应及硫上孤电子对的空间取向所引起的异构体中SCH₃、SCH₂δ值的规律变化进行了初步讨论.

Abstract: Through reductive addition of phLi to μ-S₂Fe₂(CO)₆ and nucleophilic substitution between RXand (μ-PhS)(μ-LiS)Fe₂(CO)₆ nine clusters of (μ-PhS)(μ-RS)Fe₂(CO)₆ series (Ⅰ) -(Ⅸ) have been synthesized successfully.It is shown that yields of clusters (Ⅰ) -(Ⅸ) and reactivities of RXin nucleophilic reactions depend on both structures of Rand nature of X.And according to chemical shift and integrated values of related signals of ¹HNMRpossible isomers and isomcr ratios of some clusters have been determined.In addition, it is suggested that diamagnetic aniso-tropic effects of C = Oand orientations of unshared electron pairs are likely responsible for systematic variations in δ CH₃-Sand δ CH₂-Sof cluster isomers.

TrendMD:

宋礼成, 胡青眉, 刘向阳, 王积涛. (μ-苯硫)(μ-烃硫)六碳基二铁络合物的合成及波谱研究. 高等学校化学学报, 1985, 6(2): 135.

Song Licheng, Hu Qingmei, Liu Xiangyang, Wang Jitao . Synthesis and Spectral Studies of (μ-Phenylthio)(μ-Alkylthio) Hexacarbonyldiiron Complexes. Chem. J. Chinese Universities, 1985, 6(2): 135.