炭化树脂色谱性能的理论探讨

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (12): 1063.

炭化树脂色谱性能的理论探讨

云希勤, 张尊训, 寇登民, 李艳红

南开大学化学系

收稿日期:1984-10-20 出版日期:1985-12-24 发布日期:1985-12-24

Discussion on the Chromatographic Behaviour of Carbonated Resins

Yun Xiqin, Zhang Zunxun, Kou Dengmin, Li Yanhong

Department of Chemistry, Nankai University, Tianjin

Received:1984-10-20 Online:1985-12-24 Published:1985-12-24

摘要/Abstract

摘要： 本文从热力学和动力学的角度探讨二十一种炭化树脂不同分离性能的理论基础。

Abstract: The heat of adsorption was derived from the temperature dependence of retention time for eluted peaks on a series of carbonated (pyrolyzed) resins.In view of chromatographic kinetics and thermodynamics the separative power, selectivity of the carbonaceous adsorbents and the factors influencing column efficiency are discussed theoretically.It is found that the diffusion effect controlled by inner structure of the adsorbent particle is the basic reason affecting separation and column efficiency.The conditions under which useful adsorbent could be made are revealed.

TrendMD:

云希勤, 张尊训, 寇登民, 李艳红. 炭化树脂色谱性能的理论探讨. 高等学校化学学报, 1985, 6(12): 1063.

Yun Xiqin, Zhang Zunxun, Kou Dengmin, Li Yanhong . Discussion on the Chromatographic Behaviour of Carbonated Resins. Chem. J. Chinese Universities, 1985, 6(12): 1063.