高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (12): 1051.

• 研究论文 • 上一篇    下一篇

苯并-15-冠-5的配位性能研究

金祥林1, 唐有祺1, 吴养洁2, 安浩云2, 胡宏纹2   

  1. 1. 北京大学物理化学研究所;
    2. 郑州大学化学系
  • 收稿日期:1984-07-07 出版日期:1985-12-24 发布日期:1985-12-24

Study on the Complex Property of Benzo-15-Crown-5

Jin Xianglin1, Tang Youqi1, Wu Yangjie2, An Haoyun2, Hu Hongwen2   

  1. 1. Institute of Physical Chemistry, Peking University, Beijing;
    2. Chemistry Department, Zhengzhou University, Zhengzhou
  • Received:1984-07-07 Online:1985-12-24 Published:1985-12-24

PDF (PC)

被引次数

3

摘要： 苯并-15-冠-5苦味酸钠配合物单晶由丙酮-乙醇(1:1)溶液中得到,晶体属单斜空间群C2h5-P21/n,晶体学数据:a=11.134(3)Å,6=13.541(3)Å,c=14.927(4)Å,β=93.41(2)°Å,V=2246.4Å3,Z=4,晶体结构由直接法解出,晶体结构分析结果表明,与苯环共轭的芳醚氧原子上的电子密度可通过苯环而转移。

Abstract: The single crystal of complex Na (benzo-l5-crown-5)-C6H2N5O7(C6H5N3O7=Picric acid) was obtained from the acetone-ethanol solvent.The crystal belongs to monoclinic space group C2h5-P21/n.The crystallography parameters arc:a=11.134 (3)Å,b=13.541(3)Å,c=14.927(4)Å, β=93.41 (2)°, V=2246.4Å3, Z=4.The crystal structure was solved by direct methed.The result shows that the electronic density on the aromatic ether oxygen atoms conjugated with the benzen ring can be transfered through the benzen ring.

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