高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (10): 910.

• 研究简报 • 上一篇    下一篇

过渡金属五卤苯基化合物的研究(Ⅶ)——双(二苯基烷基膦)合(σ-五溴苯基)溴化镍(Ⅱ)的合成和反应

张正之, 王序昆   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1984-06-01 出版日期:1985-10-23 发布日期:1985-10-23
  • 基金资助:

    中国科学院科学基金

Study on Transition-Metal Organic Compounds Containing Perhaloaryl Ligands(Ⅶ)——Synthesis and Reactions of Pentabromophenylnickel Complexes with Diphenylalkylphosphine

Zhang Zhengzhi, Wang Hsukun   

  1. Institute of Elemintoorganic Chemistry, Nankai University, Tianjin
  • Received:1984-06-01 Online:1985-10-23 Published:1985-10-23

摘要: 一般认为由于含卤基团较大的电负性,过渡金属有机化合物的稳定性随有机基团的氢为卤素取代而增加。在有机镍化学中,由于合成、结构和催化性能方面的兴趣,过去和最近对含有Ni—C6F5和Ni—C6Cl5键的化合物进行了广泛的合成及其反应的研究。

Abstract: The complexes of general formula (ph2PR)2Ni(C6Br5)Br(R=CH3,C2H5, n-C3H7,ph) were synthesized. Their chemical reactions with inorganic halides and pseudohalides were investigated and compared With corresponding C6Cl5 containing complexes.

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