高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (10): 894.

• 研究简报 • 上一篇    下一篇

银-1.10-菲罗啉-荧光桃红B双波长分光光度法测定微量银的研究

张有贤, 何润喜, 胡泳灵   

  1. 山西大学化学系
  • 收稿日期:1984-07-30 出版日期:1985-10-23 发布日期:1985-10-23

Dual-wavelength Spectrophotometric Determination of a Microamount of Silver with 1,10-Phenantholine and Phloxine B

Zhang Youxian, He Runxi, Hu Yongling   

  1. Department of chemistry, Shanxi University, Taiyuan
  • Received:1984-07-30 Online:1985-10-23 Published:1985-10-23

PDF (PC)

被引次数

2

摘要： 目前银-1.10-菲罗啉-曙红萃取光度法和胶束增溶光度法测定微量银已有报导,但尚未见银-1.10非罗啉-荧光桃红B胶束增溶双波长光度法测定微量银的报导。

Abstract: In the solution of Na2HPO4-NaH2PO4 at pH 5.7 and the presence of gelatin a soluble red-violet ternary complex of silver with 1,10-phenanthroliee and phlox ine Bcan be formed. On the basis of this fact we directly determined silver in aqueous solution with dual-wavelength at λR 542nm and λs 571nm. Beer's law is obeyed in the range of 0-42.7μg/25ml and Ae is 5.76×104. After separation with ion exchange this method was applied to determine a microamount of silver in anode mud and etc.

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