高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (10): 872.

• 研究简报 • 上一篇    下一篇

硼化合物研究(ⅩⅥ)——氢硼酸π-环戊二烯基双(三苯基膦)镍(Ⅱ)的合成

张伦, 黄裕源, 陈新兰, 何建社   

  1. 武汉大学化学系
  • 收稿日期:1984-07-25 出版日期:1985-10-23 发布日期:1985-10-23
  • 基金资助:

    中国科学院科学基金

Studies on Boron Compounds (ⅩⅥ)——The Syntheses of π-Cyclopentadinyl-Bis(Triphenylphosphine)- Nickel(Ⅱ) Hydroborates

Zhang Lun, Huang Yuyuan, Chen Xinlan, He Jianshe   

  1. Department of Chemistry, Wuhan University, Wuhan
  • Received:1984-07-25 Online:1985-10-23 Published:1985-10-23

摘要: MCArdle和Akker等人分别合成了[π-C5H5Ni(PPh3)2)SnCl3·S[S=CH2Cl2,(CH3)2O)租[π-C5H5Ni(PPh3)2]F等化合物.本文报告七个新的氢硼酸根(B12H122-、B10H102-、B11H14-、B3H3-、B10Cl102-B10H2Br82-、B10H4I62-)的π-一环戊二烯基双(三苯基膦)镍(Ⅱ)的合成和性质研究。

Abstract: Seven π-cycllpentadinyl-bis (triphenylphosphine)- nickel( Ⅱ) hydroborates were synthesised by the reaction between hydroborate ions (B12H122-,B10H102-,B11H14-, B3N8-, B10Cl102-, B10H2Br82-, B10H4I62-) and π-C5H5NiPPh3Cl in the presence of PPh3. These compounds were characterized by elemental analysis, IR, and molecular conductivity.The thermal stability of these complexes was examined by DTAmethod.

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