高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (10): 869.

• 研究简报 • 上一篇    下一篇

从润湿热研究HZSM-5分子筛与不同液体相互作用的特点

李玉光, 钟秋玫, 曾昭槐   

  1. 中山大学化学系
  • 收稿日期:1984-06-29 出版日期:1985-10-23 发布日期:1985-10-23

Study on the Characters of HZSM-5 Molecular Sieve Interacting with Various Liquids from Heats of Immersion

Li Yuguang, Zhong Qiumei, Zeng Zhaohuai   

  1. Department of Chemistry, Zhongshan University, Guangzhou
  • Received:1984-06-29 Online:1985-10-23 Published:1985-10-23

摘要: ZSM-5是一类新型分子筛,共物理化学性能的研究引起了广泛的兴趣。本工作测定了高温脱气的HZSM-5分子筛在正己烷、正庚烷,正癸烷、正十二烷,环己烷、苯、甲苯,邻、间、对二甲苯,甲醇和乙醇中的润湿热。

Abstract: Heat of immersion of zeolite HZSM-5 outgassed at high temperatures and in vacuum have been determined in various organic liquids. The value in terms of kilojoules per avogadro No. of unit cells, Quc, is quite different in each liquid being studied. The order of Quc was found to be n-hexane>n-heptane>n-decane> n-dodecane; benzene < toluene <p-xylene;p-xylene>xylene>xylcnc; methanol< cthanol; and the smallest in cyclohexanc.

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