高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (10): 861.

• 研究论文 • 上一篇    下一篇

原子簇配合物((C4H9)4N)2(Mo2S6O2)的合成、结构和性质研究

张致贵1, 李淑芹1, 张泽莹2, 邵美成2   

  1. 1. 吉林大学化学系;
    2. 北京大学物理化学研究所
  • 收稿日期:1984-05-03 出版日期:1985-10-23 发布日期:1985-10-23

Studies on Synthesis, Structure and Properties of the Cluster Complex [(C4H9)4N]2[Mo2S6O2]

Zhang Zhigui1, Li Shuqin1, Zhang Zeying2, Shao Meicheng2   

  1. 1. Department of Chemistry, Jilin University, Changchun;
    2. Institute of Physical Chemistry, Peking University, Beijing
  • Received:1984-05-03 Online:1985-10-23 Published:1985-10-23

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摘要： 用(NH4)2MoS4、FeCl3和(C4H9)4NBr在CH3OH-CH3ONa溶液中反应,得到了原子簇配合物[(C4H9)4N]2[Mo2S6O2]晶体,用X-射线单晶衍射方法测定了簇合物的晶体结构,晶体属空间群D2h15-Pcah,晶胞参数为a=15.876(3)Å,b=17.786(6)Å,c=31.90(1)Å,V=9008.7Å3,经块矩阵最小二乘法修正,最终得偏离因子R=0.0659,同时对簇合物的红外光谱、拉曼光谱、紫外可见光谱以及电化学性质也进行了研究。

Abstract: The crystal of the cluster complex, [(C4H9)4N]2[Mo2S6O2] was obtained by the reaction of (NH4)2MoS4, FeCl5 and (C4H9)NBr in CH3OH-CH5ONa. The crystal structure of the cluster complex was measured by X-ray. The crystal belongs to D2h15-Pcah space group. The crystal cell parameter are a=15.876(3)Å,b=17.786(6)Å,c=31.90(1)Å,V=9008.7Å3. The structure was refired by leastsquares. The value of Rwas 0.0659. The properties of IR, Raman, UV-Visible spectra and electrochemistry of the cluster complex have been investigated.

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