高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (1): 59.
• 研究简报 • 上一篇 下一篇
马桂芝1, 黎明1, 杨士英2
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Ma Guizi1, Li Ming1, Yang Shiying2
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摘要： 冠醚存在下,氯仿和水合肼反应制取重氮甲烷已有报导,但冠醚类毒性较大,而季铵盐易于制备,价格便宜。本文以自制的苄基三乙基氯化铵代替冠醚作为相转移催化剂进行该α-消去反应,制取重氮甲烷。
Abstract: Triethyl benzyl ammonium chloride was used as the phase transfer catalyst in the preparation of diazomethane from chloform, hydrazine and sodium hydroxide. By this method the use of carcinogenic N-nitroso compound as the starting material was avoidable, and the yield were over 60%.
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马桂芝, 黎明, 杨士英. 相转移催化的α-消去反应——重氮甲烷制备. 高等学校化学学报, 1985, 6(1): 59.
Ma Guizi, Li Ming, Yang Shiying. Preparation of Diazomethane by Phase Transfer Catalysis of Triethyl Benzyl Ammonium Chloride. Chem. J. Chinese Universities, 1985, 6(1): 59.
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