高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (6): 847.

• 论文 • 上一篇    下一篇

α、β、γ、δ-四苯基卟啉和稀土乙酰丙酮-α、β、γ、δ-四苯基卟啉的共振喇曼光谱研究

赵永年, 刘国发, 王桂馥, 王宇天   

  1. 吉林大学理论化学研究所
  • 收稿日期:1983-03-24 出版日期:1984-12-24 发布日期:1984-12-24

Resonance Raman Spectra of Tetraphenylporphyrin and Rare Earth Acetylacetonate-α,β,γ,δ- Tetraporphyrin

Zhao Yongnian, Liu Guofa, Wang Guifu, Wang Yutian   

  1. Institute of Theoretical Chemistry, Jilin University, Changchun
  • Received:1983-03-24 Online:1984-12-24 Published:1984-12-24

摘要: 本文用4579Å、5145Å等激发线激发,测得α、β、γ、δ、-四苯基卟啉(TP1)和12个稀土乙酰丙酮-α、β、γ、δ、-四苯基卟啉(MTPPacac)的共振喇曼光谱,对其共振特性和结构对称性进行了讨论.指认370cm-1附近谱带为MTPPacac的M—O键对称拉伸振动谱带.

Abstract: The Resonance Raman Spectra of TPP and MTPP acac were measured with 4579Å and 5145Å of Ar+ laser. Resonance speciality of spectra and structure symmetry were discussed. The band near 370cm-1 was assigned to M-Obond symmetric stretching vibration.

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