高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (6): 775.

• 论文 • 上一篇    下一篇

示波极谱滴定的研究(ⅩⅩⅠ)——铂电极上的示波极谱滴定

庄建元, 高鸿   

  1. 南京大学化学系
  • 收稿日期:1983-07-05 出版日期:1984-12-24 发布日期:1984-12-24

Investigation on Oscillopolarographic Titrations(ⅩⅪ) ——Oscillopolarographic Titrations at Pt-Electrodes

Zhuang Jianyuan, Gao Hong(H. Kao)   

  1. Chemistry Department, Nanjing University, Nanjing
  • Received:1983-07-05 Online:1984-12-24 Published:1984-12-24

摘要: 本文研究了在微铂电极上进行示波极谱滴定的方法.有些地方,它比汞电极优越.这样大大地扩充了示波极谱滴定的应用范围.

Abstract: Oscillopolarographic titrations are usually carried out at Hg-electrodeswith an applied potential of 0——2 volts. Such electrodes cannot be usedin redox titrations. It is also inconvenient to use them for titrations involving ions such as Ag+, Hg++,Cu++, Fe+++ which are reduced at near zero potentials. The use of micro Pt-electrode can solve these problems. T.itration of As(Ⅲ) .with KBrO3 in acidic solution gives very accurate results. Titration of Ag+ with I- also gives accurate results. Neutralization and complexation in titrations can also be carried out at Ptelec-trodes.

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