高等学校化学学报

高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (5): 666.

• 研究简报 • 上一篇    下一篇

一硫代焦磷酸酰胺酯的合成

陈天池, 林沐彬   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1983-01-22 出版日期:1984-10-24 发布日期:1984-10-24

Synthesis of Amide Esters of Thiopyrophosphoric Acid

Chen Tianchi, Lin Mubin   

  1. Institute of Elemento-Organic Chemistry, Nankai University, Tianjin
  • Received:1983-01-22 Online:1984-10-24 Published:1984-10-24

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摘要： TEPP和OMPA都是较早发现的具有较高杀虫活性的药剂,但由于它们对温血动物毒性高而影响广泛应用[1].许多化学家发现当焦磷酸酯中P=O上的氧原子被硫原子代替,或者烧氧基被取代氨基代替,可大大降低对温血动物的毒性而仍保持其对昆虫的毒性[2,3].

Abstract: Eight new amide esters of thiopyrophosphoric acid were prepared. Their general formula is expressed as follows:   They were proved to exist in thiono-form by IR. Some of them have high biological activities to insects.

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