高等学校化学学报

高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (4): 541.

• 论文 • 上一篇    下一篇

{Mo[S2CN(C2H5)2]4}+{MoCl6}-的合成及其晶体结构与分子结构

申成1, 孙春亭2   

  1. 1. 吉林大学理论化学研究所;
    2. 吉林大学化学系
  • 收稿日期:1983-03-05 出版日期:1984-10-24 发布日期:1984-10-24

Synthesis, Crystal Structure and Molecular Structure of {Mo[S2CN(C3H5)2]4}+{MoCl6}-

Shen Cheng1, Sun Chunting2   

  1. Jilin University, Chagchun
  • Received:1983-03-05 Online:1984-10-24 Published:1984-10-24

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摘要： 我们合成了化合物{Mo[S2CN(C2H5)2]4}+{MoCl6}-,确定了其所属晶系、空间群及晶胞参数,并确定了重原子与其它全部非氢原子坐标等.

Abstract: We have Synthesized a compound, for which molecular formula is {Mo[S2CN(C2H5)2]4}+{MoCl6}-, and determined its crystal structure by X-ray diffraction method. It is monoclinic, space group P21/a, with cell dimensions a = 14.716(6) Å, b = 16.012(6) Å, c= 17.108(9)Å, β = 102.63 (4)° and Z=4. The structure was solved by Patter son method and refined by using the Least-squares method to final consistence factors R= 0.0908, Rw= 0.0761.

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