高等学校化学学报

高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (4): 526.

• 研究简报 • 上一篇    下一篇

香茅基芳基醚类保幼激素类似物的简便合成方法

黄乃聚, 李宏善, 陶风岗, 许临晓   

  1. 复旦大学化学系
  • 收稿日期:1982-11-29 出版日期:1984-10-24 发布日期:1984-10-24

A Convenient Synthetic Method of Insetic Juveile Hormone Analogues——Citronellyl Aryl Ethers

Huang Naiju, Li Hongshan, Tao Fenggang, Xu Linxiao   

  1. Department of Chemistry, Fudan University, Shanghai
  • Received:1982-11-29 Online:1984-10-24 Published:1984-10-24

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摘要： 许多香叶基芳基醚和香茅基芳基醚已证明是有效的昆虫保幼激素[1-3].以往合成此类化合物,只能在酚与较活泼的香叶基溴的反应中使用KOH(或NaOH),与较不活泼的香茅基溴的反应则仍沿用Williamson法.我们曾报导了以聚氧乙烯类表面活性剂代替冠醚作为相转移催化剂合成醚类化合物的方法[4].

Abstract: Most of citronellyl aryl ethers and their derivatives,which are insect juvenile hormone analogues, were obtained conveniently by the phase transfer catalytic reactions of citronellyl bromide with phenols or thiophenol under the solid-liquid two phase systems and polyethylene glycol was used as phase transfer catalyst in the reaction.

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