高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (4): 503.
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曾陇梅1, 苏镜娱1, 张树德2
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Zeng Lonmei1, Su Jingyu1, Zhang Shude2
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摘要: 从毛冬青根分离出一种具有强心作用的新的三萜甙——毛冬青甙甲(I)。分析证明(Ⅰ)为毛冬青酸(Ⅱ)的β-木糖甙。(Ⅱ)是新的三萜酸,经化学反应和波谱分析推定其结构为18-去氢-20-表乌苏酸。X射线单晶衍射分析确证了毛冬青酸的结构及其立体化学。
Abstract: Ilex publesccns Hook et Am is an evergreen bush. It is used in China as a herb medicine. We have isolated from the root a new triterpenc glyco-side, namely ilexolide A, which exhibits cardiac activity.Ilexolide A ( I ) is a white amorphous solid, m. p. 214-216℃, [α]D + 54.5(c, 0.83, alc.). It was hydrolyzed to afford the aglycone, ilexolic acid (Ⅱ), m. p. 288-289℃, [α]D + 437 (c. 0.89 DMF). Ilexolide Ais xyloside of ilexolic acid (Ⅱ).Ilexolic acid, C30H46O3 (M+ 454.3463) is a new triterpene acid having the structure of (Ⅱ). Its structure has been determinated by a series of characteristic chemical reactions and spectroscopic methods. MS, NMR and IR. In order to establish the structure and stereochemistry, single crystal X-ray structure analysis has been taken.
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曾陇梅, 苏镜娱, 张树德. 毛冬青甙甲的结构研究(Ⅰ). 高等学校化学学报, 1984, 5(4): 503.
Zeng Lonmei, Su Jingyu, Zhang Shude. Studies on the Chemical Structure of Ilexolide A (Ⅰ). Chem. J. Chinese Universities, 1984, 5(4): 503.
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