高等学校化学学报

高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (3): 369.

• 论文 • 上一篇    下一篇

化学反应速率的过渡态理论

邓从豪   

  1. 山东大学理论化学研究室
  • 收稿日期:1983-01-28 出版日期:1984-06-24 发布日期:1984-06-24

THE TRANSITION STATE THEORY OF CHEMICAL REACTION RATE

Deng Conghao   

  1. Theoretical Chemistry Laboratory, Shandong University, Jinan
  • Received:1983-01-28 Online:1984-06-24 Published:1984-06-24

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摘要： 由海森堡运动方程证明了过渡态几率稳定定理.假设化学反应均经过过渡态,由此定理推导了化学反应的微观速率常数.再假设反应的始志处于热平衡,由微观速率常数推导了宏观速率常数.

Abstract: The elementary chemical reactions are assumed to pass via the transition states. From the Hersenberg equation of motion, it is proved that the probabilities of transition states are stationary. From this theorem and the Hersenberg equation of motion there are derived the micro and macro reaction rate constants of both the direct and complex models of reactions.

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