高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (2): 276.

• 研究简报 • 上一篇    下一篇

钼铁硫络合物晶体的合成、结构和性质研究

张致贵1, 王凤山1, 李淑琴1, 赵承志2, 李英2   

  1. 1. 吉林大学化学系;
    2. 吉林大学理化所
  • 收稿日期:1982-10-06 出版日期:1984-04-24 发布日期:1984-04-24

STUDIES ON THE SYNTHESIS, STRUCTURE AND PROPERTIES OF THE CRYSTAL OF Mo-Fe-S COMPLEX

Zhang Zhigui1, Wang Fengshan1, Li Shuqin1, Zhao Chengzhi2, Li Ying2   

  1. 1. Department of Chemistry, Jilin University, Changchun;
    2. Institute of Theoretical Chemistry, Jilin University, Changchun
  • Received:1982-10-06 Online:1984-04-24 Published:1984-04-24

摘要: 近几年来,模拟固氮酶的活性中心——钼铁硫原子簇化合物的合成、结构和性质研究,引起人们极大的兴趣.本文研究了一种新型的钼铁硫络合物晶体的合成、结构和性质。

Abstract: In this paper, we report a new complex of Mo-Fe-Ssynthesized by the reaction of MoCl5, FeCl2·4H2O, PhCH2SH and diethyldithiocarba-mate(DTC) in MeOH, The complex is characterized by X-ray crystal-lography,IR,UV-visible, 1H NMR, 13C NMR, and EPRspectra, and the measurements of elemental analyses and electrochemical properties. The crystal of Mo-Fe-Scomplex containing multi-bond species is quite stable.

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