高等学校化学学报 ›› 1984, Vol. 5 ›› Issue (1): 77.

• 论文 • 上一篇    下一篇

在并流交换反应器中液相水-氢同位素交换反应的研究

祁世纶1, 池东鲜1, 李永顺2, 千载虎2   

  1. 1. 大连市光明化工研究所;
    2. 吉林大学计算中心, 化学系
  • 收稿日期:1982-05-24 出版日期:1984-02-24 发布日期:1984-02-24

A STUDY OF HYDROGEN ISOTOPE EXCHANGE BETWEEN HYDROGEN AND LIQUID WATER IN THE CONCURRENT-EXCHANGE REACTOR

Qi Shilun1, Chi Dongxian1, Li Yongshun2, Qian Zai hu2   

  1. 1. Guangming Chemical Engineering Institute, Dalian;
    2. Jilin University, Changchun
  • Received:1982-05-24 Online:1984-02-24 Published:1984-02-24

摘要: 本文用憎水性D型树脂为载体,铂为活性组分,使氢-液体水之间成功地进行了氢同位素的交换反应,讨论了并流反应器的动力学方程。在17.5℃、1大气压、氢的表观速度从0.04m/sec至0.1m/sec条件下,测得的催化交换反应速度常数K=34.9×103mol/m3·hr。

Abstract: In this paper hydrogen exchange reaction between hydrogen and liquid water was performed successfully using hydrophobic resin of Dtype as support and Pt as active component.The kinetic equation in a concurrent flow reactor was discussed.At apparent velocity of hydrogen from 0.04m/sec to O.im/sec and 17.5℃ and under 1 atm the determined rate constant of the catalytic exchange reaction K is >30×103 mol/m3·hr.

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