聚α,α-二甲基-β-丙内酯与聚(1,2-丙二醇-丁二酸酯)ABA型嵌段共聚物的合成

高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (6): 782.

聚α,α-二甲基-β-丙内酯与聚(1,2-丙二醇-丁二酸酯)ABA型嵌段共聚物的合成

黎书樨, 蒋硕健, 冯新德

北京大学化学系

收稿日期:1982-03-24 出版日期:1983-12-24 发布日期:1983-12-24

SYNTHESIS OF THE ABA TYPE BLOCK COPOLYMER OF POLYPIVALOLACTONE-POLY (1,2-PROPANDIOL ADIPIC ACID ESTER)-POLYPIVALOLACTONE

Li Shuxi, Jiang Shuojian, Feng Xinde

Department of Chemistry, Peking University, Beijing

Received:1982-03-24 Online:1983-12-24 Published:1983-12-24

摘要/Abstract

摘要： 通过合成双羟端聚(1,2-丙二醇己二酸酯)(PPA),经丁二酸酐酰化得双羧端PPA,再经(Bu₄N)₂CO₃-THF铵化得铵化PPA,最后用铵化PPA与α,α-二甲基-β-丙内酯(PVL)嵌段共聚,首次合成了PPVL-PPA-PPVL的ABA型脂肪族聚酯嵌段共聚物。

Abstract: A new block copolymer of ABA type aliphatic polyester, polypiv-alolactone-poly (1 ,2-propandiol adipic acid ester) -polypivalolactone (PPVL-PPA-PPVL) was prepared through the synthesis of dihydroxy terminate PPA, dicarboxyl terminate PPA with succinic anhydride and then tetrabutyl ammonium salt of dicarboxyl terminate PPA by treating with (Bu₄N)₂CO₃-THF and finally by the block copolymerization of tetrabutyl ammonium salt of dicarboxyl terminate PPA with PVL. The conversion of the block copolymerization of PVL was 93-96% and the efficiency of this polymerization was 95-96%,

TrendMD:

黎书樨, 蒋硕健, 冯新德. 聚α,α-二甲基-β-丙内酯与聚(1,2-丙二醇-丁二酸酯)ABA型嵌段共聚物的合成. 高等学校化学学报, 1983, 4(6): 782.

Li Shuxi, Jiang Shuojian, Feng Xinde . SYNTHESIS OF THE ABA TYPE BLOCK COPOLYMER OF POLYPIVALOLACTONE-POLY (1,2-PROPANDIOL ADIPIC ACID ESTER)-POLYPIVALOLACTONE. Chem. J. Chinese Universities, 1983, 4(6): 782.