高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (6): 727.

• 论文 • 上一篇    下一篇

多齿配体的合成

胡宏纹, 张壮予   

  1. 南京大学化学系
  • 收稿日期:1982-05-06 出版日期:1983-12-24 发布日期:1983-12-24

THE SYNTHESIS OF MULTIDENTATE LIGANDS

Hu Hongwen, Zhang Zhuangyu   

  1. Department of Chemistry, Nanjing University, Nanjing
  • Received:1982-05-06 Online:1983-12-24 Published:1983-12-24

摘要: 苯环上有羟基或甲氧基的苄醇在硫酸存在下与乙腈或丙烯腈作用,得到了相应的酰胺。产率一般在90%以上。乙酰胺水解成二胺后与水杨醛作用生成相应的双Schiff碱。

Abstract: Benzyl alcohols containing a hydroxy or methoxy group on the benzene ring were treated with acetonitrile or acrylonitrile in the presence of sulfuric acid to give the corresponding amides in excellent yields, and bis-acetam ides were hydrolyzed, the corresponding diamines were produced and further condensed with salicylaldehyde to produce the expected Schiff bases.

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