5-二甲氨基-1,2,3-三硫环己烷草酸盐的薄层色谱分析

高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (6): 722.

5-二甲氨基-1,2,3-三硫环己烷草酸盐的薄层色谱分析

龙韫先, 叶春芝

南开大学元素有机化学研究所

收稿日期:1982-04-27 出版日期:1983-12-24 发布日期:1983-12-24

THIN LAYER CHROMATOGRAPHIC ANALYSIS OF 5-DIMETHYLAMINO-1, 2,3-TRITHIANE HYDROGENOXALATE

Long Yunxian, Ye Chunzhi

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin

Received:1982-04-27 Online:1983-12-24 Published:1983-12-24

摘要/Abstract

摘要： 本文用薄层色谱法以丙酮:甲醇:水:氯仿=12:3:3:5为展开剂对以盐形式存在的(这里有图片19830609-722-1.GIF)化合物进行了分析,并研究了它的色谱行为的特殊性。通过R_f值对照法、薄层-红外光谱法对待测组分进行了鉴定。建立了双波长薄层色谱扫描碘显色外标单点校正定量法,并对不同定量方法进行了比较。测量结果相对误差和相对偏差均为±2％。

Abstract: By using TLC method the compound(这里有图片19830609-722-1.GIF) existing in its salt form was separated from its decomposed products and by-products with the developing agent consisting of acetone:methanol: water:chloroform = 12:3:3:5. Its special TLC behavior was studied and proved.It was identified by the R_f value method and the TLC-IR method. By using the dual-wavelength TLC-scanner its content was determined with iodine vapor visualization and the external standard one-point calibration method. By comparing the results obtained with different methods a new alternative sample application method is presented, with which the disadvantage of the unstability of iodine vapor method usually encountered has been overcome and the accuracy has been improved. The relative error of the recovery rate is within ± 2 %,

TrendMD:

龙韫先, 叶春芝. 5-二甲氨基-1,2,3-三硫环己烷草酸盐的薄层色谱分析. 高等学校化学学报, 1983, 4(6): 722.

Long Yunxian, Ye Chunzhi . THIN LAYER CHROMATOGRAPHIC ANALYSIS OF 5-DIMETHYLAMINO-1, 2,3-TRITHIANE HYDROGENOXALATE. Chem. J. Chinese Universities, 1983, 4(6): 722.