高等学校化学学报

高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (5): 661.

• 研究简报 • 上一篇    下一篇

威尔逊方程能量参数的回归

侯镜德, 方舟   

  1. 浙江大学中心实验室
  • 收稿日期:1982-03-15 出版日期:1983-10-24 发布日期:1983-10-24

REGRESSION FOR ENERGY PARAMETERS OF WILSON EQUATION

Hou Jingde, Fang Zhou   

  1. Central Laboratory, Zhejiang University, Hangzhou
  • Received:1982-03-15 Online:1983-10-24 Published:1983-10-24

PDF (PC)

被引次数

3

摘要： 目前利用单端无限稀释活度系数来求得整个浓度范围内的汽液平衡数据有一定的缺陷[1,2]。本文由实验数据回归得威尔逊方程能量参数,并求得了与经典法测定的相一致的汽液平衡数据。

Abstract: Depending on experimental datums, energy parameters of Wilson equation were regressed. Activity coefficients at finite concentrations were calculated.The predictive datums were in good agreement with the ordinary experimental datums reported in literatures.

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