高等学校化学学报

高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (1): 139.

• 研究快报 • 上一篇    

等离子体聚四氟乙烯的ESR研究

宋瑞芳1, 岳世泰1, 刘军1, 陈捷2, 陈占勋2, 刘学恕2   

  1. 1. 吉林大学理论化学研究所;
    2. 中国科学院长春应用化学研究所
  • 收稿日期:1982-10-13 出版日期:1983-02-24 发布日期:1983-02-24

ESR STUDIES OF PLASMA-POLYMERIZED TETRAFLUOROETHYLENE

Song Ruifang1, Yue Shitai1, Liu Jun1, Chen Jie2, Chen Zhanxun2, Liu Xueshu2   

  1. 1. Institute of Theoretical Chemistry, Jilin University, Changchun;
    2. Institute of Applied Chemistry, Academia Sinica, Changchun
  • Received:1982-10-13 Online:1983-02-24 Published:1983-02-24

PDF (PC)

被引次数

5

摘要： 目前,对等离子体聚合机理,即自由基和离子聚合机理仍在争论之中[1-6],ESR的研究对探讨等离子体聚四氟乙烯(PPTFE)聚合机理将是有价值的。

Abstract: In this paper the species and the properties of the free-radicals in synthesis reaction of the plasma-polymerized tetrafluoroethylene have been studies by means of the ESR. We first get about 160 hyperfine splitting lines of plasma-polymerized tetrafluoroethylene in gas conden-sates, and investigated the mechanism of the free-radicals in the plasma-polymerized tetrafluoroethylene.

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