Abstract: Some dicyclopentadienyl compounds of titanium, Cp₂Ti(OCH₂C₆H₅) Cl, Cp₃Ti[OCH(CH₃)C₆H₅]Cl and Cp₂Ti(OCH₂CH₂C₆H₅)Cl, have been synthesized with good yields. They react readily with electrophilic reagents such as hydrogen chloride, acetyl chloride or benzoyl chloride and thionyl chloride, to give dicyclopentadienyl titanium dichloride. The reactions of these compounds with water, alcohol and tetrahydrofuran afforded the corresponding complexes. The IR spectra and the thermal stability of these compounds have also been studied.