高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (1): 1.

• 论文 •    下一篇

沸石分子筛的生成机理与晶体生长(Ⅴ)——L型沸石晶体生长动力学

徐如人, 李守贵   

  1. 吉林大学化学系
  • 收稿日期:1981-07-30 出版日期:1983-02-24 发布日期:1983-02-24

THE MECHANISM OF FORMATION AND CRYSTAL GROWTH OF MOLECULAR SIEVE ZEOLITE (Ⅴ) -THE KINETICS OF CRYSTAL GROWTH OF L-TYPE ZEOLITE

Xu Ruren(Hsu Rhu-Reng), Li Shougui   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1981-07-30 Online:1983-02-24 Published:1983-02-24

摘要: 通过加晶种的方法在一定范围内完成了L型沸石的晶体生长与成核等过程的分离。发现L型沸石的晶体生长符合2/3级反应,并考察了影响晶体生长的各种因素。提出了L型沸石晶体生长的模型。

Abstract: We were able to achieve a strict separation of processes of nucleation and growth for the crystallization of L-type zeolite over a considered range by adding crystal seeds of L-type zeolite in initial gel. The kineticsof crystal growth of L-type zeolite obeys a kinetic law of order 2/3. Notonly were reported influences of various parameters on the crystal growth rate, but also the apparent activation energy of growth of L-type zeolite was obtained. Based on the experimental results, a model for the explanation of crystal growth of L-type zeolite is developed.

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