高等学校化学学报 ›› 1982, Vol. 3 ›› Issue (2): 279-280.

• 研究快报 • 上一篇    

O-碳硼烷醚类衍生物的合成

张正之, 申泮文   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1981-02-21 出版日期:1982-04-24 发布日期:1982-04-24

SYNTHESIS OF ETHEREAL DERIVATIVES OF o-CARBORANE

Zhang Zhengzhi, Shen Panwen   

  1. The Institute of Elemento-Organic Chemistry, Nankai University, Tianjin
  • Received:1981-02-21 Online:1982-04-24 Published:1982-04-24

摘要: 碳硼烷是一类对空气、热和化学作用稳定的有机硼化合物。到目前已制得了几百个各种类型的碳硼烷衍生物,但关于其醚类衍生物则报导得很少,对称性的醚类衍生物几乎未见报导[1-4]。就合成方法而言,直接由炔化物合成1,2-二碳对称取代的碳硼烷也是少见的。我们由炔化物与双-(二乙硫醚)合十二氢癸硼烷直接合成了两个新的对称性o-碳硼烷醚类衍生物,扩展了用直接法合成o-碳硼烷衍生物的途径。

Abstract: Presented here is a note for the preparation of two new o-R(Ar) OCH2CB10 H10CH2O(Ar)R  compounds by treating B10H12 [(C3H5)2S]2 with R(Ar) OCH2C = CCH2O(Ar)R. Through this synthesis, the scope of application of the direct synthesis of substituted o-carborane derivatives from RC≡CR compounds has been enlarged.