高等学校化学学报 ›› 1982, Vol. 3 ›› Issue (2): 205-209.
• 论文 •
Song Hongzi, Wang Naixing
Abstract: The cathodic stripping behaviour of iodide films at the hanging mercury drop electrode in a series of electrlytes and the use of complexing agent as masking agent have been investigated. Under the experimental conditions without complexing agent, heavy metal elements showed serirus interference. The interference from less than 1000-fold molar amounts of Zn(II), Cd(II), Pb(II) and less than200-fold molar amounts of Cu(II) could be eliminated by the complex formation of those with EDTA, DCTAor DTPA, The optimum condition for the determination of iodide is as f ollowsielec-trolyte 0.02M EDTA (0.01M DCTAor 0.02M DTPA), deposition potential -0.05V (vs. Ag-AgCl), deposition time 2 min., voltage-sweep rate 100mV/sec. Afair reproducibility is obtained in the above procedure and a good proportionality between the peak values of the cathodic stripping current and iodide concentration (10-6 - 5× 10-8M) has been observed. The detection limit is 6.3×10-9M, The recommended method was sucessfully applied to the direct determination of trace iodine in drinking water and common salt. For tap water a mean value of 14.6 ppb I- was found, while for mineral water the value was 156 ppb I-, and for the common salt, was 977 ppb I-. The relative standard deviation for iodine is 3.85%, 3.24%, 1.5% respectively.
宋鸿镃, 汪乃兴. 碘的阴极溶出伏安法研究[J]. 高等学校化学学报, 1982, 3(2): 205-209.
Song Hongzi, Wang Naixing . STUDIES ON THE CATHODIC STRIPPING VOLTAMMETRY OF IODINE[J]. Chemical Journal of Chinese Universities, 1982, 3(2): 205-209.