高等学校化学学报 ›› 1981, Vol. 2 ›› Issue (2): 195.

• 论文 • 上一篇    下一篇

硅-芳键的断裂反应

周秀中, 张增佑, 梁格, 郭聪元, 磨强中, 谢庆兰, 徐善生   

  1. 南开大学化学系元素有机化学研究所
  • 收稿日期:1980-06-07 出版日期:1981-04-24 发布日期:1981-04-24

THE CLEAVAGE OF ARYL-SILICON BONDS

Zhou Xiuzhong, Zhang Zengyou, Liang Ge, Guo Congyuan, Me Qiangzhong, Xie Qinglan, Xu Shansheng   

  1. The Institute of Elemento-Oryanic Chemistry, Department of Chemistry, Nankai University, Tianjin
  • Received:1980-06-07 Online:1981-04-24 Published:1981-04-24

摘要: 利用等摩尔竞争法我们研究了五种芳基三甲基硅烷与氯化氢的非均相断裂反应。用气体色谱法对各竞争反应产物进行定量分析,求出各断裂产物的相对性产率,结果表明其活性顺序是与相应的均相断裂反应相一致的。

Abstract: By means of equimolecular competing reaction we investigated the cleavage of five aryl trimethyl silanes by hydrogen chloride.The cleavage products were quantitatively analyzed by gas cbromato-graphy. The selective yield of every cleavage product showed that the reactive sequance was in accordance with the result of corresponding homogeneous cleavage.

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