高等学校化学学报 ›› 1980, Vol. 1 ›› Issue (1): 23.

• 论文 • 上一篇    下一篇

二苯并-18-冠-6与硫氰酸钇络合物的研究(Ⅰ)--合成与性质

王耕霖, 张允什, 姚心侃, 阎世平, 王连元   

  1. 南开大学化学系
  • 收稿日期:1979-12-18 出版日期:1980-06-24 发布日期:1980-06-24

STUDIES ON THE COMPLEX OF Y(NCS)3AND DIBENZO-18-CROWN-6-I--SYNTHESIS AND CHARACTERIZATION

Wang Genglin, Zhang Yunshi, Yao Xinkan, Yan Shiping, Wang Lianyuan   

  1. Department of Chemistry, Nankai University
  • Received:1979-12-18 Online:1980-06-24 Published:1980-06-24

摘要: 我们制得了硫氨酸轮与二苯并-18-冠-6(DBC)的固体络合物,进行了元素分析、X光衍射、红外光谱、紫外光谱和差热、热重分析,对其合成条件及性质进行了一些探讨。

Abstract: The complex of Y(NCS)3and dibenzo-18-crown-6 has been prepared in solid state and characterized by elemental analyses,X-ray diffraction,infrared and ultraviolet spectra,as well as thermogravimetric (TG) and differential thermal analyses (DTA).The complex formed is proved to be Y (dibenzo-18-crown-6) (NCS)3Besides,a brief discussion on the conditions of complexation by rare earth elements with crown ethers was performed.

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