高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (1): 19.doi: 10.7503/cjcu20190518
章凌1,段宏昌2,谭争国2,吴勤明1,孟祥举1,*(
),肖丰收1,*()
收稿日期:2019-10-10
出版日期:2020-01-10
发布日期:2019-12-20
通讯作者:
孟祥举,肖丰收
E-mail:mengxj@zju.edu.cn;fsxiao@zju.edu.cn
基金资助:
ZHANG Ling1,DUAN Hongchang2,TAN Zhengguo2,WU Qinming1,MENG Xiangju1,*(),XIAO Fengshou1,*()
Received:2019-10-10
Online:2020-01-10
Published:2019-12-20
Contact:
Xiangju MENG,Fengshou XIAO
E-mail:mengxj@zju.edu.cn;fsxiao@zju.edu.cn
Supported by:摘要：
系统总结了作为柴油车尾气消除反应(NH3-SCR)催化材料的八元环沸石分子筛(CHA, AEI, RTH)的研究进展, 讨论了不同方法合成的八元环沸石分子筛在NH3-SCR反应中的性能差异, 并对未来八元环分子筛的发展趋势进行了展望.
中图分类号:
TrendMD:
章凌,段宏昌,谭争国,吴勤明,孟祥举,肖丰收. 用于柴油车尾气消除反应(NH3-SCR)的八元环沸石分子筛研究进展. 高等学校化学学报, 2020, 41(1): 19.
ZHANG Ling,DUAN Hongchang,TAN Zhengguo,WU Qinming,MENG Xiangju,XIAO Fengshou. Recent Advances in the Preparation of 8MR Zeolites for the Selective Catalytic Reduction of NOx(NH3-SCR) in Diesel Engines †. Chem. J. Chinese Universities, 2020, 41(1): 19.
Fig.1 Diagrammatic representation of the route for eliminating diesel exhaust
Fig.2 Solvent-free synthesis of zeolites from solid raw materials[30] Copyright 2012, American Chemical Society.
Fig.3 NOx conversion in the NH3-SCR reaction over the fresh(Cu2.2-SSZ-13 and Cu2.8-SSZ-13) and hydrothermally aged(Cu2.2-SSZ-13-HTA and Cu2.8-SSZ-13-HTA) Cu-SSZ-13 catalysts with different Cu loadings[32] Feed: 0.05%(volume fraction) NO, 0.05%(volume fraction) NH3, 5%(volum fraction) H2O, 10%(volume fraction) O2, and N2 as a balance gas. Copyright 2019, American Chemical Society.
Fig.4 NO conversions as a function of temperature on the Cu-SSZ-13(15)(A) and Cu-SSZ-13(4)(B) catalysts[40] Feed(volume fraction): 0.05% NO, 0.05% NH3, 10% O2, 5% H2O, and N2 as a balance gas. Copyright 2017, Elsevier.
Fig.5 NO conversions as a function of temperature on various fresh(A, C) and 800 ℃ aged(B, D) RE ion exchanged Cu-SSZ-13(4)[41] Feed(volume fraction): 0.05% NO, 0.05% NH3, 10% O2, 5% H2O, and N2 as a balance gas. Copyright 2019, Royal Society of Chemistry.
Fig.6 Mechanism on the synthesis of Cu-SSZ-13 zeolites templated from Cu-TEPA[43] Copyright 2011, Royal Society of Chemistry.
Fig.7 NOx conversions over the Cu3.8-SSZ-13 catalyst under various conditions[44] GHSV(Gas hour space velocity)=400000 h-1. Copyright 2014, American Chemical Society.
Fig.8 Transformation synthesis of aluminosilicate SSZ-39 zeolite from ZSM-5 and Beta zeolite[55] Copyright 2019, Royal Society of Chemistry.
Fig.9 Diagrammatic representation of the route for synthesizing aluminosilicate SSZ-39 zeolite[56] Copyright 2019, Royal Society of Chemistry.
Fig.10 NOx conversion of Cu-RTH catalysts(A) and hydrothermally aged Cu-RTH catalysts(B) with different Cu loadings in the NH3-SCR reaction[64] Feed(volume fraction): 0.05% NO, 0.05% NH3, 5% O2, 5% H2O, and N2 as a balance gas. Copyright 2019, Royal Society of Chemistry.
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