尺寸比例可调的Au-Ni双金属纳米颗粒的制备

doi:10.7503/cjcu20170145

高等学校化学学报 ›› 2017, Vol. 38 ›› Issue (11): 1921.doi: 10.7503/cjcu20170145

• 研究论文: 无机化学 • 上一篇下一篇

尺寸比例可调的Au-Ni双金属纳米颗粒的制备

韩天昊, 梁福鑫, 杨振忠()

中国科学院化学研究所, 高分子物理与化学国家重点实验室, 北京 100190

收稿日期:2017-03-09 出版日期:2017-11-10 发布日期:2017-10-30
作者简介:联系人简介: 杨振忠, 男, 博士, 研究员, 博士生导师, 主要从事高分子复合功能体系方法学及材料性质研究. E-mail: yangzz@iccas.ac.cn
基金资助:
国家自然科学基金(批准号: 51233007)资助

Synthesis of Au-Ni Bimetallic Nanoparticles with Tunable Aspect Ratio^†

HAN Tianhao, LIANG Fuxin, YANG Zhenzhong^*()

State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry,Chinese Academy of Sciences, Beijing 100190, China

Received:2017-03-09 Online:2017-11-10 Published:2017-10-30
Contact: YANG Zhenzhong E-mail:yangzz@iccas.ac.cn
Supported by:
† Supported by the National Natural Science Foundation of China(No.51233007)

摘要/Abstract

摘要：

本文采用贵金属诱导还原法制备了一种Ni端尺寸可调的Au-Ni双金属纳米颗粒. 该反应以十八胺为还原剂, 硝酸镍和氯金酸为反应物, 反应中Au³⁺首先被还原成Au⁰, 随着温度上升, Ni²⁺从Au⁰获得电子而被还原成Ni⁰, 十八胺持续提供电子, 得到了雪人状的Au-Ni双金属纳米颗粒. 采用I₂/KI水溶液和0.5%(质量分数)盐酸分别对Au端和Ni端进行择性蚀刻, 通过调节蚀刻时间, 连续调控两端尺寸, 可以达到完全刻蚀, 最终制备了一种两端尺寸比例连续可调的Au-Ni双金属纳米颗粒. 蚀刻后得到的新鲜表面为进一步功能复合提供了反应场所.

关键词: 双金属纳米颗粒, 反应时间, 选择性刻蚀, 结构调控

Abstract:

In this paper, the Au-Ni bimetallic nanoparticles with tunable aspect ratio of Au to Ni were synthesized by noble-metal-induced-reduction strategy. Octadecylamine is reducible at high temperatures thus it was used as a reducing agent. As the temperature increased gradually, Au³⁺ was reduced by octadecylamine to form Au⁰. After that, Ni²⁺ was reduced to Ni⁰ by obtaining electrons from Au⁰ at 220 ℃. Octadecylamine provided electrons to Au³⁺ continuously during the reaction. The size of Ni side could be tunable by changing the reaction time at 220 ℃. Au side and Ni side could be selectively etched with aqueous I₂/KI and 0.5%(mass fraction) aqueous HCl, respectively. The size of Au-Ni bimetallic nanoparticles could be tuned continuously by etching for varied time. Au side or Ni side could be completely etched separately, remaining Ni nanoparticles or Au nanoparticles. The fresh surface obtained after etching Au side or Ni side provided a site of chemical reaction for further compositing functional substances. This method is attractive owing to the easiness to continuously tuning aspect ratio of the bimetallic nanoparticles. On the other hand, composition of the bimetallic nanoparticles is also flexibly tunable using different reactants.

Key words: Bimetallic nanoparticles, Reaction time, Selectively etching, Morphology control

中图分类号:

O614

TrendMD:

韩天昊, 梁福鑫, 杨振忠. 尺寸比例可调的Au-Ni双金属纳米颗粒的制备. 高等学校化学学报, 2017, 38(11): 1921.

HAN Tianhao, LIANG Fuxin, YANG Zhenzhong. Synthesis of Au-Ni Bimetallic Nanoparticles with Tunable Aspect Ratio^†. Chem. J. Chinese Universities, 2017, 38(11): 1921.

图/表 8

Scheme 1 Continuously tuning aspect ratio of Au-Ni bimetallic nanoparticles by wet etching

Fig.1 HRTEM image(A), line-scanning EDS analysis(B), XRD pattern(C) and dispersibility and magnetic response in THF(D) of the Au-Ni bimetallic nanoparticles after reaction for 10 min

Fig.2 TEM images of the Au-Ni nanoparticles after reaction for 5(A), 10(B) and 15 min(C)

Fig.3 UV-Vis spectra(A) and DLS result(B) of the Au-Ni nanoparticles after reaction for 5 min(a), 10 min(b) and 15 min(c)

Fig.4 TEM images of Au-Ni bimetallic nanoparticles after being etched with aqueous I2/KI for 5 min(A), 10 min(B) and 15 min(C)The insets illustrate the corresponding Janus particles.

Fig.5 UV-Vis spectra(A)and DLS result(B) of the Au-Ni bimetallic nanoparticles after being etched for 5 min(a), 10 min(b) and 15 min(c)

Fig.6 TEM images of Au-Ni bimetallic nanoparticles after being etched with 0.5% aqueous HCl for 10 min(A), 30 min(B) and 50 min(C) The insets illustrate the corresponding Janus particles.

Fig.7 UV-Vis spectra(D) and DLS result(E) of the Au-Ni bimetallic nanoparticles after being etched for 10 min(a), 30 min(b) and 50 min(c)

参考文献 26

[1]	Rodriguez J. A., Goodman D. W., Science,1992, 257(5072), 897-903
[2]	Jaime M., Movshovich R., Stewart G. R., Beyermann W. P., Berisso M. G., Hundley M. F., Canfield P. C., Sarrao J. L., Nature,2000, 405(405), 160-163
[3]	Yi Q. F., Li L., Song L. H., Niu F. J., Chin. J. Inorg. Chem., 2010, 26(9), 1600-1604
	(易清风, 李磊, 宋李红, 牛凤娟. 无机化学学报, 2010, 26(9), 1600-1604)
[4]	Ji X. H., Wang L. Y., Yuan H., Ma L., Bai Y. B., Li T. J., Chem. J. Chinese Universities,2010, 31(10), 1556-1560
	(纪小会, 王连英, 袁航, 马岚, 白玉白, 李铁津. 化学学报, 2003, 61(10), 1556-1560)
[5]	Pellegrino T., Fiore A., Carlino E., Giannini C., Cozzoli P. D., Ciccarella G., Respaud M., Palmirotta L., Cingolani R., Manna L., J. Am. Chem. Soc., 2006, 128(20), 6690-6698
[6]	Xu D., Liu Z. P., Yang H. Z., Liu Q. S., Zhang J., Fang J. Y., Zou S. Z., Sun K., Angew. Chem., Int. Ed., 2009, 48(23), 4217-4221
[7]	Krenke T., Duman E., Acet M., Wassermann E. F., Moya X., Manosa L., Planes A., Nat. Mater., 2005, 4(6), 450-454
[8]	Habas S. E., Lee H., Radmilovic V., Somorjai G. A., Yang P. D., Nat. Mater., 2007, 6(9), 692-697
[9]	Gschneidner K., Russell A., Pecharsky A., Morris J., Zhang Z. H., Lograsso T., Hsu D., Lo C. H. C., Ye Y. Y., Slager A., Kesse D., Nat. Mater., 2003, 2(9), 587-591
[10]	Roh K. H., Martin D. C., Lahann J., Nat. Mater., 2005, 4(10), 759-763
[11]	Jiang S., Chen Q., Tripathy M., Luijten E., Schweizer K. S., Granick S., Adv. Mater., 2010, 22(10), 1060-1071
[12]	Wu B. H., Zhang H., Chen C., Lin S. C., Zheng N. F., Nano Res., 2010, 2(12), 975-983
[13]	Wetz F., Soulantica K., Falqui A., Respaud M., Snoeck E., Chaudret B., Angew. Chem., Int. Ed., 2007, 46(37), 7209-7211
[14]	Fu Q., Saltsburg H., Flytzani-Stephanopoulos M., Science,2003, 301(5635), 935-938
[15]	Gorin D. J., Sherry B. D., Toste F. D., Chem. Rev., 2008, 108(8), 3351-3378
[16]	Wang D. S., Xie T., Li Y. D., Nano Res., 2009, 2(1), 30-46
[17]	Jin C., Chen Q. H., Zheng M. J., Zhao P., Li Q., Cui N. Q., J. Inorg. Mater., 2016, 31(3), 241-247
	(金朝, 陈其汉, 郑梦佳, 赵鹏, 李倩, 崔小强. 无机材料学报, 2016, 31(3), 241-247)
[18]	Wang K., Xu L., Chen H. Z., Qiao H. Y., Chen C., Zhang N., Chem. J. Chinese Universities,2010, 31(4), 723-727
	(王凯, 徐力, 陈恒泽, 乔慧颖, 陈超, 张宁. 高等学校化学学报, 2016, 37(4), 723-727)
[19]	Bao Y., Calderon H., Krishnan K. M., Chem. J. Chinese Universities,2010, 31(5), 1941-1944
[20]	Wei W., Li S., Millstone J. E., Banholzer M. J., Chen X., Xu X., Schatz G. C., Mirkin C. A., Angew. Chem., Int. Ed., 2009, 48(23), 4210-4212
[21]	Mandal S., Krishnan K. M., J. Mater. Chem., 2007, 17(4), 372-376
[22]	Wang D. S., Li Y. D., J. Am. Chem. Soc., 2010, 132(18), 6280-6281
[23]	Carbone L., Cozzoli P. D., Chem. J. Chinese Universities,2010, 31(5), 449-493
[24]	Bai L., Kuang Y., Luo J., Evansa D. J., Sun X. M., Chem. Commun., 2012, 48(55), 6963-6965
[25]	Cai Z., Kuang Y., Luo L., Wang L. R., Sun X. M., Chem. J. Chinese Universities,2010, 31(9), 1265-1269
	(蔡钊, 邝允, 罗亮, 王利人, 孙晓明. 化学学报, 2013, 71(9), 1265-1269)
[26]	Li D. S., Komarneniw S., J. Am. Ceram. Soc., 2006, 89(89), 1510-1517

尺寸比例可调的Au-Ni双金属纳米颗粒的制备

Synthesis of Au-Ni Bimetallic Nanoparticles with Tunable Aspect Ratio^†

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 26

相关文章 5

编辑推荐

Metrics

本文评价

[1]	王霞, 刘彦吉, 贾永锋, 吉磊, 胡全丽, 段莉梅, 刘景海. 含氮多孔纳米碳纤维的制备及对锂硫电池容量的提高[J]. 高等学校化学学报, 2020, 41(4): 829.
[2]	李晓莉, 黄亮, 段红娟, 张力, 张海军. 石墨烯负载Pt/Co双金属纳米颗粒催化剂的制备及催化制氢性能[J]. 高等学校化学学报, 2019, 40(8): 1662.
[3]	孟庆男, 王凯, 汤玉斐, 赵康. 二氧化硅中空微球的制备及结构调控[J]. 高等学校化学学报, 2018, 39(11): 2550.
[4]	刘林林, 杨忠志. 耗散粒子动力学与可极化ABEEM力场结合模拟嵌段共聚物自组装形态调控[J]. 高等学校化学学报, 2015, 36(11): 2179.
[5]	孙佳宁, 谢续明. 环氧树脂共混物相结构的调控方法研究[J]. 高等学校化学学报, 1998, 19(11): 1857.

尺寸比例可调的Au-Ni双金属纳米颗粒的制备

Synthesis of Au-Ni Bimetallic Nanoparticles with Tunable Aspect Ratio†

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 26

相关文章 5

编辑推荐

Metrics

本文评价

Synthesis of Au-Ni Bimetallic Nanoparticles with Tunable Aspect Ratio^†