高等学校化学学报 ›› 2016, Vol. 37 ›› Issue (10): 1799-1803.doi: 10.7503/cjcu20160139

• 分析化学 • 上一篇    下一篇

甲基苯丙胺电化学检测条件的优化

张雪娜1, 钟新文1, 钟岩1, 陆海彦2()   

  1. 1. 吉林警察学院刑事技术系, 长春 130117
    2. 吉林大学化学学院, 长春 130012
  • 收稿日期:2016-03-08 出版日期:2016-10-10 发布日期:2016-09-23
  • 作者简介:联系人简介: 陆海彦, 男, 博士, 教授, 主要从事电化学方面的研究. E-mail:lhy@jlu.edu.cn
  • 基金资助:
    国家自然科学基金(批准号: 21273097)和吉林省教育厅“十二五”科学技术项目(吉教科合字[2014]第629号)资助

Optimization of Conditions of the Electrochemical Detection of Methamphetamine

ZHANG Xuena1, ZHONG Xinwen1, ZHONG Yan1, LU Haiyan2,*()   

  1. 1. Department of Criminal Technology, Jilin Police College, Changchun 130117, China
    2. College of Chemistry, Jilin University, Changchun 130012, China
  • Received:2016-03-08 Online:2016-10-10 Published:2016-09-23
  • Contact: LU Haiyan E-mail:lhy@jlu.edu.cn
  • Supported by:
    † Supported by the National Natural Science Foundation of China(No.21273097) and the Twelfth Five-year-plan for Science and Technology Research of Department of Education of Jilin Province, China(No.[2014]629)

摘要:

采用电化学方法检测甲基苯丙胺, 探讨了不同扫描速度、 初始浓度、 pH值、 电极处理温度及干扰物对检测的影响, 获得了甲基苯丙胺电化学检测的最佳条件. 结果表明, 工作电极为掺硼金刚石薄膜电极, 扫描速度为50~100 mV/s, 初始浓度小于100 mg/L, pH=7.0及电极处理温度为100 ℃时, 甲基苯丙胺的检测速度最快, 检测结果最好, 同时干扰物对于电化学方法检测甲基苯丙胺无明显影响.

关键词: 电化学法, 甲基苯丙胺, 循环伏安法

Abstract:

Electrochemical method was used to detect methamphetamine(MA) and the effects of different detection conditions, such as the scan speed, the initial concentration of MA, pH value, electrode processing temperature and disruptors, on the electrochemical detection of MA were investigated to find out the optimal conditions for the electrochemical detection of MA. The results show that with BDD thin film electrode as the working electrode and at a scan rate of 50—100 mV/s, initial concentration of lower than 100 mg/L, pH=7.0 and electrode processing temperature of 100 ℃, the detection rate of MA is the fastest with best results, and the disruptors have no obvious effect on the detection of MA.

Key words: Electrochemical method, Methamphetamine(MA), Cyclic voltammetry(Ed.: S, Z, M)

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