Zn(Ⅱ),Cd(Ⅱ)与混合配体构筑三维贯穿金属有机配位聚合物的合成、结构与荧光性能

doi:10.3969/j.issn.0251-0790.2012.09.003

高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (09): 1889.doi: 10.3969/j.issn.0251-0790.2012.09.003

• 研究论文: 无机化学 • 上一篇下一篇

Zn(Ⅱ),Cd(Ⅱ)与混合配体构筑三维贯穿金属有机配位聚合物的合成、结构与荧光性能

薛铭, 陈思如, 郭莉佳, 裘式纶

吉林大学无机合成与制备化学国家重点实验室, 长春 130012

收稿日期:2012-06-18 出版日期:2012-09-10 发布日期:2012-08-14
通讯作者: 裘式纶,男,博士,教授,博士生导师,主要从事无机固体材料化学研究.E-mail:sqiu@mail.jlu.edu.cn E-mail:sqiu@mail.jlu.edu.cn
基金资助:
国家"九七三"计划项目(批准号: 2011CB808703)和国家自然科学基金(批准号: 91022030, 21101072)资助.

Synthesis, Structure and Luminescence Properties of Two 3D Interpenetrating Metal-organic Coordination Polymers of Mixed Ligands with Zn(Ⅱ) and Cd(Ⅱ)

XUE Ming, CHEN Si-Ru, GUO Li-Jia, QIU Shi-Lun

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Received:2012-06-18 Online:2012-09-10 Published:2012-08-14

摘要/Abstract

摘要：

在中温混合溶剂热条件下, 分别用锌离子和镉离子与二羧酸和二吡啶基配体反应合成出2个新颖的金属有机配位聚合物[Zn(BPDC)(BPE)·(DMF)₂](JUC-91)和[Cd(BPDC)(BPE)·(DMF)₂](JUC-92)[BP-DC:4,4'-联苯二羧酸,BPE:反式1,2-二(4-吡啶基)乙烯,DMF:N,N'-二甲基甲酰胺], 并通过X射线单晶衍射、元素分析、热重分析、粉末X射线衍射、拓扑结构分析和荧光光谱对化合物的结构、组成和性质进行了表征. X射线单晶衍射结果表明, 化合物JUC-91和JUC-92均具有三维开放骨架结构, 其中, JUC-91具有五重贯穿的金刚石拓扑结构, JUC-92具有双重贯穿的简单立方格子结构.

关键词: 金属有机配位聚合物, 4,4'-联苯二羧酸, 反式1,2-二(4-吡啶基)乙烯, 贯穿结构

Abstract:

Two new metal-organic coordination polymers [Zn(BPDC)(BPE)·(DMF)₂](JUC-91) and [Cd(BPDC)(BPE)·(DMF)₂](JUC-92)[BPDC:4,4'-biphenyldicarboxylic acid,BPE:trans-bis1,2-二(4-pyridyl)ethylene,DMF:N,N'-dimethylformamide] were synthesized by self-assembly of mixed ligands and corresponding transition metal salts under mild conditions and characterized by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, topology analysis and powder X-ray diffraction. X-Ray crystallography revealed that JUC-91 and JUC-92 exhibited three-dimensional structures with fivefold interpenetrating diamond network and twofold interpenetrating primitive cubic network, respectively. In addition, luminescence properties of JUC-91 and JUC-92 were characterized.

Key words: Metal-organic coordination polymer, 4,4'-Biphenyldicarboxylic acid, trans-Bis(4-pyridyl)ethylene, Interpenetrating network

中图分类号:

O614

TrendMD:

薛铭, 陈思如, 郭莉佳, 裘式纶. Zn(Ⅱ),Cd(Ⅱ)与混合配体构筑三维贯穿金属有机配位聚合物的合成、结构与荧光性能. 高等学校化学学报, 2012, 33(09): 1889.

XUE Ming, CHEN Si-Ru, GUO Li-Jia, QIU Shi-Lun. Synthesis, Structure and Luminescence Properties of Two 3D Interpenetrating Metal-organic Coordination Polymers of Mixed Ligands with Zn(Ⅱ) and Cd(Ⅱ). Chem. J. Chinese Universities, 2012, 33(09): 1889.

参考文献

[1] Zhang J. P., Zhang Y. B., Lin J. B., Chen X. M.. Chem. Rev.[J], 2012, 112(2): 1001-1033

[2] Zhang W., Xiong R. G.. Chem. Rev.[J], 2012, 112(2): 1163-1195

[3] CHEN Wan(陈万), SU Sheng-Qun(苏胜群), SONG Shu-Yan(宋术岩), SONG Xue-Zhi(宋学志), ZHANG Hong-Jie(张洪杰). Chem. J. Chinese Universities(高等学校化学学报)[J], 2012, 33(2): 215-218

[4] HU Kong-Qiu(胡孔球), KOU Hui-Zhong(寇会忠). Chem. J. Chinese Universities(高等学校化学学报)[J], 2012, 33(5): 892-896

[5] CHEN Wen-Xian(陈文娴), WU Geng-Huang(吴耿熀), ZHUANG Gui-Lin(庄桂林), KONG Xiang-Jian(孔祥建), LONG La-Sheng(龙腊生), HUANG Rong-Bin(黄荣彬), ZHENG Lan-Sun(郑兰荪). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(3): 519-526 [6 ] Lin S. W., Wu Q., Wang E. B.. Chem. Res. Chinese Universities[J], 2012, 28(3): 375-378

[7] Wang J., Liu Z. Q., Su T. T.. Chem. Res. Chinese Universities[J], 2011, 27(3): 354-357

[8] Jin R. Z., Bian Z., He Y. B., Gao L. X.. Chem. Res. Chinese Universities[J], 2010, 26(6): 857-861

[9] ZHANG Yue-Biao(章跃标), ZHOU Hao-Long(周浩龙), HE Chun-Ting(何纯挺), XUE Wei(薛玮), ZHANG Jie-Peng(张杰鹏), CHEN Xiao-Ming(陈小明). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(3): 497-502

[10] JIN Qiang(金强), ZHAO Jiao(赵娇), SHI Xin(石鑫). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(8): 1496-1501

[11] Song W. C., Pan Q. H., Song P. C., Zhao Q., Zeng Y. F., Hu T. L., Bu X. H.. Chem. Commun.[J], 2010, 46: 4890-4892

[12] Xue M., Zhu G. S., Ding H., Wu L., Zhao X. J., Jin Z., Qiu S. L.. Cryst. Growth Des.[J], 2009, 9: 1481-1488

[13] Xue M., Zhu G. S., Zhang Y. J., Fang Q. R., Hewitt I. J., Qiu S. L.. Cryst. Growth Des.[J], 2008, 8: 427-434

[14] Lan A. J., Li K. H., Wu H. H., Olson D. H., Emge T. J., Ki W., Hong M. C., Li J.. Angew. Chem. Int. Ed.[J], 2009, 48: 2334-2338

[15] Takashima Y., Martinez V. M., Furukawa S., Kondo M., Shimomura S., Uehara H., Nakahama M., Sugimoto K., Kitagawa S.. Nature Commun.[J], 2011, 2: 168

[16] Sheldrick G. M.. SHELXTL-97, Version 5.1, Madison: Bruker AXS. Inc., 1997

[17] O’Keeffe M., Yaghi O. M.. Reticular Chemistry Structure Resource, Arizona State University: Tempe, AZ, 2005; http://rcsr.anu.edu.au/

[18] Mir M. H., Koh L. L., Tan G. K., Vittal J. J.. Angew. Chem. Int. Ed.[J], 2010, 49: 390-393

[19] Wen L. L., Dang D. B., Duan C. Y., Li Y. Z., Tian Z. F., Meng Q. J.. Inorg. Chem.[J], 2005, 44: 7161-7170

[20] Lin J. G., Zang S. Q., Tian Z. F., Li Y. Z., Xu Y. Y., Zhu H. Z., Meng Q. J.. CrystEngComm.[J], 2007, 9: 915-921

[21] Cui P., Chen Z., Gao D. L., Zhao B., Shi W., Cheng P.. Cryst. Growth Des.[J], 2010, 10: 4370-4378

[22] XUE Ming(薛铭), LI Yang-Xue(李阳雪), HUANG Lin(黄麟), QIU Shi-Lun(裘式纶). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(3): 515-518

[23] Shi X., Zhu G. S., Fang Q. R., Wu G., Tian G., Wang R. W., Zhang D. L., Xue M., Qiu S. L.. Eur. J. Inorg. Chem.[J], 2004: 185-191

[24] Shi X., Zhu G. S., Wang X. H., Li G. H., Fang Q. R., Zhao X. J., Wu G., Tian G., Xue M., Wang R. W., Qiu S. L.. Cryst. Growth Des.[J], 2005, 5: 341-346

[25] Bai H. Y., Ma J. F., Yang J., Zhang L. P., Ma J. C., Liu Y. Y.. Cryst. Growth Des.[J], 2010, 10: 1946-1959

[26] Chen W. T., Wang M. S., Liu X., Guo G. C., Huang J. S.. Cryst. Growth Des.[J], 2006, 10: 2289-2300

[27] Chang Z., Zhang A. S., Hu T. L., Bu X. H.. Cryst. Growth Des.[J], 2009, 9: 4840-4846

[28] Yu X. Y., Ye L., Zhang X., Cui X. B., Zhang J. P., Xu J. Q., Hou Q., Wang T. G.. Dalton Trans.[J], 2010, 39: 10617-10625

Zn(Ⅱ),Cd(Ⅱ)与混合配体构筑三维贯穿金属有机配位聚合物的合成、结构与荧光性能

Synthesis, Structure and Luminescence Properties of Two 3D Interpenetrating Metal-organic Coordination Polymers of Mixed Ligands with Zn(Ⅱ) and Cd(Ⅱ)

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