Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (7): 1099.

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The Catalytic Reduction of NO by CO on Sm2-x,SrxNiO4

LOU Hui1, CHEN Ping1, BAO Yun1, GE Yu-Ping1, MA Fu-Tai1, LU Yue-Qing2   

  1. 1. Department of Chemistry, Hangzhou University, Hangzhou, 310028;
    2. Department of Biochemistry, Shaoxing Normal School, Shaoxing
  • Received:1994-10-24 Revised:1995-02-15 Online:1995-07-24 Published:1995-07-24

Abstract: The catalytic activity of perovskite series Sm2-xSrxNiO4(x=0. 4, 0.5, 0. 6, 0. 8, 1.0, 1. 2, 1. 4, 1. 5) has been studied for the reduction of NO by CO. The results indicate that the route at low temperature and low degree of substitution of lanthanum by strontium is different from that at high temperature and high degree of Sr2+substitution, which is closely related to the structure of the compounds, to the sum of the enthalpies of the metal-oxygen bonds in the compounds, to the apparent activation energies for the reduction of NO as well as to the behaviour of oxygen desorption from the compounds.

Key words: Sm2-xSrxNiO4, NO reduction, CO oxidation

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