Synthesis of a Series of Linear Clusters [M2M′S4O4]2-and Relationship Between Spectra and Structure

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (1): 14.

• Articles • Previous Articles Next Articles

Synthesis of a Series of Linear Clusters [M₂M′S₄O₄]^2-and Relationship Between Spectra and Structure

NIU Shu-Yun¹, YANG Bing¹, LUO Kai¹, WANG wei-Ling¹, ZHANG Zhi-Gui¹, SHI Long²

1. Department of Chemistry, Jilin University, Changchun 130023;
2. Norman Bethune University of Medical Sciences, Changchun

Received:1995-03-27 Online:1996-01-24 Published:1996-01-24

Abstract

Abstract: Six linear clusters [Et₁N]₂[M₂M′S₄O₄](M=Mo,W;M′=Co, Ni, Fe)wereprepared and chracterized by means of UV-Vis, IRand XPSspectra. By comparing andstudying the spectra, the d electron configuration,valence of central metal M′and the mi-cro-environment of[M′S₄] are discussed. Based on this,the configuration of anion of theclusters was inferred and the stability of the clusters was discussed.

Key words: Linear cluster, Synthesis, Spectrum assignment, Structure

TrendMD:

NIU Shu-Yun, YANG Bing, LUO Kai, WANG wei-Ling, ZHANG Zhi-Gui, SHI Long. Synthesis of a Series of Linear Clusters [M₂M′S₄O₄]^2-and Relationship Between Spectra and Structure[J]. Chem. J. Chinese Universities, 1996, 17(1): 14.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Sicong, PANG Beibei, LIU Xiaokang, DING Tao, YAO Tao. Application of XAFS Technique in Single-atom Electrocatalysis [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220487.
[3]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[4]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[5]	JIANG Bowen, CHEN Jingxuan, CHENG Yonghua, SANG Wei, KOU Zongkui. Recent Progress of Single-atom Materials in Electrochemical Biosensing [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220334.
[6]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[7]	WU Yushuai, SHANG Yingxu, JIANG Qiao, DING Baoquan. Research Progress of Controllable Self-assembled DNA Origami Structure as Drug Carrier [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220179.
[8]	LI Lin, QI Fenglian, QIU Lili, MENG Zihui. Dynamic Amorphous Photonic Structure Patterns Assembled by Hexagonal Magnetic Nanosheets [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220123.
[9]	JIA Yanggang, SHAO Xia, CHENG Jie, WANG Pengpeng, MAO Aiqin. Preparation and Lithium Storage Performance of Pseudocapacitance-controlled Perovskite High-entropy Oxide La（Co_0.2Cr_0.2Fe_0.2Mn_0.2Ni_0.2）O₃ Anode Materials [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220157.
[10]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[11]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[12]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[13]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[14]	ZHAO Yingzhe, ZHANG Jianling. Applications of Metal-organic Framework-based Material in Carbon Dioxide Photocatalytic Conversion [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220223.
[15]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.

Synthesis of a Series of Linear Clusters [M₂M′S₄O₄]^2-and Relationship Between Spectra and Structure

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments