A Study on the Phase Equilibrium of the Ternary System of Yb(ClO4)3-BAPHDCA H2O3BAPHDCAH2O(30℃) and the Preparation of Ternary Complex

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (2): 181.

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A Study on the Phase Equilibrium of the Ternary System of Yb(ClO₄)₃-BAPHDCA H₂O₃BAPHDCAH₂O(30℃) and the Preparation of Ternary Complex

CUI Bin, CHEN Kai-Xun, TANG Zong-Xun, GUO Zhi-Zhen

Department of Chemistry; Department of Chemical Engineering, Northwest University, Xi'an, 710069

Received:1998-01-21 Online:1999-02-24 Published:1999-02-24

Abstract

Abstract: The solubility properties of the title syste MAt 30 in the whole concentration range have been systematically investigated by phase equilibrium method. The results indicated that there is a ternary complex, which is incongruently soluble in water, formed in the system:Yb(BAPHDCA)₂(ClO₄)₃4H₂O. Under the direction of phase equilibrium results, the complex has been prepared and characterized by chemical and elemental analysis, IRspectra, TG-DTG and X-ray powder diffraction.

Key words: N, N-Bis(antipyrine-4'-y-l)1, 6-hexanedicaboxamide, Ytterbium perchlorate, Phase equilibrium, Ternary system

CLC Number:

O642

TrendMD:

CUI Bin, CHEN Kai-Xun, TANG Zong-Xun, GUO Zhi-Zhen . A Study on the Phase Equilibrium of the Ternary System of Yb(ClO₄)₃-BAPHDCA H₂O₃BAPHDCAH₂O(30℃) and the Preparation of Ternary Complex[J]. Chem. J. Chinese Universities, 1999, 20(2): 181.

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A Study on the Phase Equilibrium of the Ternary System of Yb(ClO₄)₃-BAPHDCA H₂O₃BAPHDCAH₂O(30℃) and the Preparation of Ternary Complex

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