Negative Photochromic Properties and Alkali-metal Cation Recognition of Crowned Spirobenzopyrans

Abstract

Abstract: The photochromism and alkali metal cation-induced coloration of indolinospiropyrans possessing monoaza-benzo-15-C-5 at 8-position were investigated by UV-Vis spectrometry. The results indicated that these compounds show negative photochromic properties differed from those of crowned spiropyran derivatives reported, and have an excellent recognition of alkali metal canon.

Key words: Crown ether, Spriopyran, Nagative photochromism, Alkali metal ion, Recognition ability

CLC Number:

O626

TrendMD:

LIU Sheng-Hua, WU Cheng-Tai . Negative Photochromic Properties and Alkali-metal Cation Recognition of Crowned Spirobenzopyrans[J]. Chem. J. Chinese Universities, 2000, 21(5): 734.

References

Related Articles 15

[1]	CAO Lei, CHEN Meijun, YUAN Gang, CHANG Gang, ZHANG Xiuhua, WANG Shengfu, HE Hanping. Solution-gated Graphene Field Effect Transistor Sensor Based on Crown Ether Functionalization for the Detection of Mercury Ion [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210688.
[2]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[3]	CHENG Xiankun, HOU Xue, TIAN Huan, ZHANG Menglong, WEI Hao, ZHAO Zhuo. Synthesis of Macrocyclic Thiacrown Ethers and Their Selective Extraction for Ag(Ⅰ) and Tl(Ⅰ) ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1881.
[4]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[5]	FANG Qiusheng, LI Yanhong, CHEN Ling. Synthesis of Novel Anthracene Crown Ethers and the Guest Binding Behaviors^† [J]. Chem. J. Chinese Universities, 2017, 38(9): 1563.
[6]	WU Ruofei, CHU Yanqiu, XU Chongsheng, LIU Zhipan, DING Chuanfan. Fragmentation Reaction of Complexes of Alkali Metal Cations with Tripeptides in Gas Phase^† [J]. Chem. J. Chinese Universities, 2016, 37(12): 2150.
[7]	WEI Wanghui, WANG Qing, CHU Yanqiu, WANG Rizhi, DING Chuanfan. Fragmentation Reactions of Complexes of Alkali Metal Ions with Pentaserine, Pentaleucine and Pentalysine in Gas Phase^† [J]. Chem. J. Chinese Universities, 2014, 35(1): 37.
[8]	WANG Li-Hua, JIANG Shan, ZHANG Zhi-Jun, ZHANG Heng-Yi, LIU Yu. Synthesis and Ion Recognition Behavior of Benzo-18-crown-6 Modified Perylene Bisimide [J]. Chem. J. Chinese Universities, 2013, 34(9): 2108.
[9]	ZHANG Yu-Jian, HE Zhen-Feng, LI Guo-Wen*. Synthesis and Property of an Amphiphilic Polymer Containing Nucleobases and Aza-crown Ethers [J]. Chem. J. Chinese Universities, 2010, 31(7): 1456.
[10]	WEN Yong-Hong¹, YANG En-Bo², FU Li-An¹, FANG Sheng-Qiang¹. Influence of Lithium Salts Anion and Sidegroup of 15-Crown-5 Series on the Far IR Shift of Solid Lithium Complexes with Crown Ethers [J]. Chem. J. Chinese Universities, 2007, 28(2): 224.
[11]	HAN Jian-Rong, ZHANG Heng-Yi, LIU Yu. Synthesis and Selective Binding for Metal Ion of Double-armed Benzo-15-crown-5 [J]. Chem. J. Chinese Universities, 2005, 26(7): 1273.
[12]	YANG Min, ZENG Zhao Rui, QIU Wen Li, HUANG Zai Fu . Preparation and Investigation of a Solid-phase Microextraction Fiber Coated with Open Chain Crown Ether Containing Vinyl Group [J]. Chem. J. Chinese Universities, 2003, 24(4): 615.
[13]	GUO Xue-Yan, ZHU Wen-Xiang, YAN Xi, WANG Ru-Ji, LI Yong. Syntheses and Crystal Structures of Complexes Zinc and Copper(Ⅱ) Nitrates with 1,10-Dioxa-4,7,13,16-tetraazacyclooctadecane [J]. Chem. J. Chinese Universities, 2002, 23(10): 1842.
[14]	TONG Yue-Hong, HUANG Zai-Fu, SHAO Yuan-Hua, WANG Er-Kang . Sodium Ion Transfer Across Micro Water/1,2-DCE Interface Facilitated by Liquid Crystal Crown Ether [J]. Chem. J. Chinese Universities, 2001, 22(11): 1803.
[15]	HE Lian, HU Ji-Ming, YE Yong, SHI Hao, NIU Fei, GU Ying-Hong, NIU Chang-Rong. Raman and Infrared Spectra of Bisamides-bis(crown ether) Compounds [J]. Chem. J. Chinese Universities, 1999, 20(9): 1362.