Perturbation Effect of Ultra Trace Hydrogen Peroxide on the MnSO4-KBrO3-Diacetone Oscillating Chemical Reaction

Abstract

Abstract: The similarities between life processes that exhibit oscillatory behavior and chemical oscillating systems impel people to think that the biological and abiological phenomena conform to the same law. Oscillating chemical systems have been the focus of much research in the area of theoretical and experimental chemical dynamics as well as analytical sciences in recent years, but the studies on the perturbation species are kept around the concentration level of 10^-7 mol/L. In our experiment, an amazed phenomenon was found. Ultra trace level (10^-20 mol/L) of H₂O₂ can cause so magnitude influence on the macro system (MnSO₄-KBrO₃-diacetone oscillating chemical system) that the effect can be observed by a macroscopical method. When the concentration of H₂O₂ is above 10^-13mol/L , the oscillation can even be stopped. Afurther study on the mechanism will doubtlessly help to understand the mystery of life, such as the sudden cardiopathy and the metabolism failure.

Key words: Oscillating chemical reaction, Hydrogen peroxide, CSTR(continuous-flow stirred tank reactor), Nonlinear kinetics

CLC Number:

O657

TrendMD:

ZHANG Ke, CAI Ru-Xiu, MA Wan-Hong, LIN Zhi-Xin, GAN Nan-Qin. Perturbation Effect of Ultra Trace Hydrogen Peroxide on the MnSO₄-KBrO₃-Diacetone Oscillating Chemical Reaction[J]. Chem. J. Chinese Universities, 2000, 21(3): 377.

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Perturbation Effect of Ultra Trace Hydrogen Peroxide on the MnSO₄-KBrO₃-Diacetone Oscillating Chemical Reaction

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