Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (2): 337.

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Studies on Nano-cobalt/Ethanol Sol Prepared by Pulsed Laser Ablation

ZHANG Yi1,2, CHEN Wen-Zhe2, ZHANG Wen-Gong3   

  1. 1. Experiment Center, Fujian Normal University, Fuzhou 350007, China;
    2. College of Material Science and Engineering, Fuzhou University, Fuzhou 350002, China;
    3. Institute of Polymer Science, Fujian Normal University, Fuzhou 350007, China
  • Received:2002-05-31 Online:2003-02-24 Published:2003-02-24

Abstract: A novel nano-cobalt/ethanol sol was firstly obtained by pulsed laser ablation on the interface of solid and flowing-liquid. TEM results show that nano-cobalt particles size is about 30 nm. Electronic diffraction and XRD analysis both indicate that the nano-cobalt is non-crystalline. It was found that the stretching vibration of associating hydroxyl(γOH) and the deformation vibration of C-H in ethanol are strengthened, but stretching vibration of γC-O in primary hydroxyl of ethanol is restrained through the FTIR spectrum. The UV-Vis results show that there are one strong absorption peak at 231.99 nm due to primary nano-cobalt particles and two medium absorption peaks at 273.00 and 308.56 nm due to quantum confine effect.

Key words: Cobalt/etanol sol, Nano-material, Pulsed laser ablation

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