Synthesis of Spherical YBO3∶Eu Phosphors by Spray Pyrolysis Method

Abstract

Abstract: Non-aggregated and spherical YBO₃∶Eu phosphor particles with a narrow size distribution(1—2 μm) were first prepared by a two-step spray pyrolysis process. The effects of PEG concentration on the phosphor morphology and emission intensity, the annealing temperature on the crystallinity, the precursor concentration on the particle size and the doping concentration of Eu³⁺ on the emission intensity were investigated, respectively. The phosphor particle size can be controlled by changing the concentrations of precursor and PEG. Solid and spherical phosphor particles with a size of 1—2 μm were obtained with a certain precursor concentration (0.07 mol/L) and PEG concentration (0.04 mol/L), and the aggregation between particles did not appear even after annealing at a high temperature. Higher or lower concentration of PEG makes the phosphor particles broken or hollow, which will low the emission intensity. The results of XRD indicate that the powders begin to crystallize at 700 ℃ and completely crystallized at 1 100 ℃, and the optimum concentration for Eu³⁺ was determined to be 10%(molar fraction) of Y³⁺ in YBO₃ host lattices.

Key words: Luminescence, Spray pyrolysis, Spherical phosphor, Yttrium borate, Europium

CLC Number:

O614

TrendMD:

WANG Lie-Song, LIN Jun, ZHOU Yong-Hui . Synthesis of Spherical YBO₃∶Eu Phosphors by Spray Pyrolysis Method[J]. Chem. J. Chinese Universities, 2004, 25(1): 11.

[1]	WANG Ruina, SUN Ruifen, ZHONG Tianhua, CHI Yuwu. Fabrication of a Dispersible Large-sized Graphene Quantum Dot Assemblies from Graphene Oxide and Its Electrogenerated Chemiluminescence Behaviors [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220161.
[2]	SUN Xuefeng, RENAGUL Abdurahman, YANG Tongsheng, YANG Qianting. Synthesis and Luminescence Properties of Cr，In Co-doped Small Size MgGa₂O₄ Near-infrared Persistent Luminescence Nanoparticles [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210850.
[3]	ZHOU Yonghui, LI Yao, WU Yuxuan, TIAN Jing, XU Longquan, FEI Xu. Synthesis of A Novel Photoluminescence Self-healing Hydrogel [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210606.
[4]	ZHANG Liling, LIU Liu, ZHENG Mingqiu, FANG Wenkai, LIU Da, TANG Hongwu. Dual Signal Detection of HPV16 DNA by CRISPR/Cas12a Biosensing System Based on Upconversion Luminescent Resonance Energy Transfer [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220412.
[5]	DU Shunfu, WANG Wenjing, EL⁃SAYED El⁃Sayed M., SU Kongzhao, YUAN Daqiang, HONG Maochun. A Chemiluminescent Zirconocene Coordination Tetrahedron [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210628.
[6]	WEI Minmin, YUAN Ze, LU Min, MA Hui, XIE Xiaoji, HUANG Ling. Recent Advances in Lanthanide Doped Upconversion Nanoparticle-Metal Organic Framework Composites [J]. Chem. J. Chinese Universities, 2021, 42(8): 2313.
[7]	MENG Yan, WANG Xiufeng, ZHANG Li, LIU Minghua. Helical Structure and Circularly Polarized Luminescence of Naphthalene Derived Amphiphilic Molecules Through Air/water Interface Assembly [J]. Chem. J. Chinese Universities, 2021, 42(4): 1253.
[8]	ZHANG Huidong, GU Panpan, ZHANG Fang, DU Mingxu, YE Kaiqi, LIU Yu. Design and Electroluminescence Properties of Narrow-spectrum Phosphorescent Complexes [J]. Chem. J. Chinese Universities, 2021, 42(12): 3571.
[9]	XI Jing, CHEN Na, YANG Yanbing, YUAN Quan. Recent Progress in Controlled Synthesis of Persistent Luminescence Nanomaterials for Diagnosis Applications [J]. Chem. J. Chinese Universities, 2021, 42(11): 3247.
[10]	WANG Bodong, PAN Meichen, ZHUO Ying. Construction of Electrochemiluminescence Sensing Interface Based on Silver Nanoclusters-Silica Nanoparticles and Biomolecular Recognition [J]. Chem. J. Chinese Universities, 2021, 42(11): 3519.
[11]	WANG Bolun, ZONG Siyu, LI Jiyang. Recent Progress on Photoluminescent Zeolite-based Composite Materials [J]. Chem. J. Chinese Universities, 2021, 42(1): 299.
[12]	LIAO Ni, ZHANG Jieyuan, HUANG Ziyang, ZHAO Yanxi, CHAI Yaqin, YUAN Ruo, ZHUO Ying. Construction of High Efficiency Uric Acid Sensor Based on the co-Crystal Enhanced Electrochemiluminescence from 9,10-Diphenylanthracene-perylene Microcrystals [J]. Chem. J. Chinese Universities, 2020, 41(9): 1989.
[13]	CAO Zhiyuan, SUN Hui, SU Bin. Electrochemiluminescence of Quantum Dots: Research Progress and Future Perspectives [J]. Chem. J. Chinese Universities, 2020, 41(9): 1945.
[14]	XIE Ziyi, LIU Dan, ZHANG Yihan, LIU Qingqing, DONG Huanli, HU Wenping. Recent Advances on High Mobility Emissive Anthracene-derived Organic Semiconductors ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1179.
[15]	ZHAO Ziyi,ZHENG Hongzhi,XU Yan. Multi-color Circularly Polarized Luminescence Properties of Cellulose Nanocrystal ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1120.

Synthesis of Spherical YBO₃∶Eu Phosphors by Spray Pyrolysis Method

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments