Synthesis, Characterization and Crystal Structure of a New Layered Heterometallic Coordination Polymer {[(CuL)2Sr(H2O)·Sr2(H2O)7]·2H2O·0.5CH3OH}n</

Abstract

Abstract: A copper-strontium heterometallic coordination polymer was synthesized and characterized by elemental analysis and IR spectra. The crystal structure was determined by single-crystal X-ray diffraction analyses. The title complex is a 2D coordination polymer with the chemical formula {[(CuL)₂Sr(H₂O)·Sr₂(H₂O)₇]·2H₂O·0.5CH₃OH}_n, where H4L=N-(2-hydroxybenzamido)-N'-(3-carboxylsalicylidene)ethylenediamine. Its structural unit is comprised of two adjacent units, which polymerized with each other to form a new layered heterometallic coordination polymer.

Key words: Copper, Strontium, Heterometallic coordination polymer, Crystal structure

CLC Number:

O614

TrendMD:

TAO Ruo-Jie¹, LIU Bao-Lin¹, LI Fu-An¹, CHENG Yan-Xiang², NIU Jing-Yang¹. Synthesis, Characterization and Crystal Structure of a New Layered Heterometallic Coordination Polymer {[(CuL)₂Sr(H₂O)·Sr₂(H₂O)₇]·2H₂O·0.5CH₃OH}_{ndoi: .}

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URL: http://www.cjcu.jlu.edu.cn/EN/

http://www.cjcu.jlu.edu.cn/EN/Y2006/V27/I8/1400

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[1]	ZHENG Anni, JIN Lei, YANG Jiaqiang, WANG Zhaoyun, LI Weiqing, YANG Fangzu, ZHAN Dongping, TIAN Zhongqun. Effects of 5，5-Dimethylhydantoin on Electroless Copper Plating [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220191.
[2]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[3]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[4]	WU Fengtian, LI Jun, SUN Yijia, ZENG Rong, REN Han, LIU Xiuping, ZHANG Caihong, YAN Fangming, WU Ling, CUI Chunna. Fibroin Assisted Copper-promoted C-N Coupling Reaction [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210707.
[5]	CHU Yao, WANG Shuo, ZHANG Zinuo, WANG Yibo, CAI Yibing. Preparation and Properties of Cu Particles Loaded Foam-based Phase Change Composites [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210619.
[6]	ZHOU Ning, TANG Xiaohua, CAO Hong, ZHA Fei, LI Chun, XIE Chunyan, XU Mingping, SUN Yige. Preparation， Characterization and Degradation to BPA of Pomegranate-like Gel Microsphere Entrapmented Laccase [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210705.
[7]	ZHANG Tao, SHAO Liang, ZHANG Menghui, MA Zhonglei, LI Xiaoqiang, MA Jianzhong. Preparation and Properties of Bifunctional Polydimethysiloxane/Copper Nanowire Composite Films [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220359.
[8]	JIANG Baozheng, HUANG Wenting, LIU Wenbao, GUO Rongsheng, XU Chengjun, KANG Feiyu. Preparation of Nano-copper Modified Three-dimensional Zinc Mesh Electrode and Its Performance as Anode for Zinc-ion Batteries [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220257.
[9]	WANG Jie, HUO Haiyan, WANG Yang, ZHANG Zhong, LIU Shuxia. General Strategy for In situ Synthesis of NENU-n Series Polyoxometalate-based MOFs on Copper Foil [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210557.
[10]	LI Weiqing, JIN Lei, YANG Jiaqiang, Wang Zhaoyun, YANG Fangzu, ZHAN Dongping, TIAN Zhongqun. Effects of Additive on the Electrodeposition and Coating Structure in a Novel System of Electronic Copper Electroplating [J]. Chem. J. Chinese Universities, 2021, 42(9): 2919.
[11]	ZHONG Shengguang, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Theoretical Study on Direct Conversion of CH₄ and CO₂ into Acetic Acid over MCu₂O_x（M = Cu²⁺， Ce⁴⁺， Zr⁴⁺） Clusters [J]. Chem. J. Chinese Universities, 2021, 42(9): 2878.
[12]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[13]	PU Weiwen, SHI Yongsen, LIU Jianfeng, KE Dehong, WU Xiaolan, XU Sheng. Synthesis of （E）-α-Hydroxyethyl-α，β-unsaturated Aldehydes with Tetrahydrofuran as Carbonyl Source [J]. Chem. J. Chinese Universities, 2021, 42(12): 3641.
[14]	SUN Qiangqiang, CAO Baoyue, ZHOU Chunsheng, ZHANG Guochun, WANG Zenglin. Enhancing Hydrogen Evolution Performance of a Regular Cube NiCu Nanocrystalline Electrocatalyst Fabricated by Normal Pluse Electrodeposition ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1287.
[15]	LIU Hengshuo,YU Zhiquan,SUN Zhichao,WANG Yao,LIU Yingya,WANG Anjie. Copper Salt Anchored on a Covalent Organic Framework as Heterogeneous Catalyst for Chan-Lam Coupling Reaction ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1091.