Chem. J. Chinese Universities ›› 2006, Vol. 27 ›› Issue (4): 692.

• Contents • Previous Articles     Next Articles

Oxidation Desulfurization from Fluid Catalytic Cracking Gasoline via Photocatalysis

ZHAO Di-Shun*, LIU Cui-Wei, MA Si-Guo   

  1. College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology,
    Shijiazhuang 050018, China
  • Received:2005-04-30 Online:2006-04-10 Published:2006-04-10
  • Contact: ZHAO Di-Shun,E-mail: zhao_dsh@hebust.edu.cn

Abstract:

Oxidation desulfurization via photocatalysis was investigated by using thiophene in xylol as the model compound, and hydrogen peroxide is used as the oxidant. The effects of hydrogen peroxide mass fraction, high shear agitation time, titanium dioxide mass on the desulfurization efficiency of FCC gasoline were also investigated. Under suitable conditions, the desulfurization rate of the model compound and of FCC gasoline can reach 80% and 59%, respectively. The conductivity and GC-FPD analyses show that the sulfurcontaining compounds are converted into the substance with a higher polarity.

Key words: FCC gasoline; Model; Photocatalysis; Oxidation;

CLC Number: 

TrendMD: