Ultrafast Synthesis of Ultrasmall Fe3+-doped BiF3 Nanoparticles at Room Temperature

doi:10.7503/cjcu20200137

Abstract

Abstract: Facile synthesizing ultrasmall nanoparticles at room temperature can promote the large-scale applications of nanotechnology. However, successful cases are barely reported, because ultrasmall nanoparticles usually need high temperature for nucleation and ligands for reducing the surface energy. Herein, we took cubic BiF₃ as an example to synthesize ultrasmall Fe³⁺-doped BiF₃ nanoparticles at room temperature. For only one minute, Smaller Fe³⁺ ions can successfully substitute for bigger Bi³⁺ ions in the BiF₃ lattice. With increasing the Fe³⁺ doping content, the particle size of BiF₃:Fe³⁺ nanoparticles decrease continuously. Amazing, ultrasmall Fe³⁺-doped BiF₃ nanoparticles about 6.9 nm in size can be obtained when the Fe³⁺ doping content reaches 0.119. Moreover, the doping of Fe³⁺ ions gives rise to a remarkable changes in the band structure of BiF³:Fe³⁺-x samples. The ultrasmall Fe³⁺-doped BiF₃ nanoparticles reported here may find potential applications in photocatalyst and fluorescent material.

Key words: Room temperature, Ultrasmall nanoparticles, BiF₃

CLC Number:

O611.4

TrendMD:

LENG Zhihua, LI Xiangyi. Ultrafast Synthesis of Ultrasmall Fe³⁺-doped BiF₃ Nanoparticles at Room Temperature[J]. Chem. J. Chinese Universities, 2020, 41(8): 1739.

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Ultrafast Synthesis of Ultrasmall Fe³⁺-doped BiF₃ Nanoparticles at Room Temperature

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