Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (9): 1813.doi: 10.7503/cjcu20150385
• Polymer Chemistry • Previous Articles Next Articles
WANG Jun1, HUO Hongliang1, LI Cuiqin1,*(), MA Lili1, SHI Weiguang1, CHEN Shuai2
Received:
2015-05-14
Online:
2015-09-10
Published:
2015-08-21
Contact:
LI Cuiqin
E-mail:dqpilicuiqin@126.com
Supported by:
CLC Number:
TrendMD:
WANG Jun, HUO Hongliang, LI Cuiqin, MA Lili, SHI Weiguang, CHEN Shuai. Synthesis of Novel Dendritic Bridging Nickel Complex for Oligomerization of Olefins†[J]. Chem. J. Chinese Universities, 2015, 36(9): 1813.
Compd. | IR(cm-1) | ||||||
---|---|---|---|---|---|---|---|
ν—CONH | δ—CONH | ν—N< | νN—Ni | ||||
Ligand | 3288 | 2950 | 1680 | 1640 | 1540 | 1120 | |
Complex | 3244 | 2939 | 1617 | 1600 | 1570 | 1116 | 644 |
Table 1 Infrared spectral data of ligand and complex
Compd. | IR(cm-1) | ||||||
---|---|---|---|---|---|---|---|
ν—CONH | δ—CONH | ν—N< | νN—Ni | ||||
Ligand | 3288 | 2950 | 1680 | 1640 | 1540 | 1120 | |
Complex | 3244 | 2939 | 1617 | 1600 | 1570 | 1116 | 644 |
Entry | t/min | p/MPa | n(Al)/n(Ni) | 10-6Activity/ [g·(mol Ni·h)-1] | Selectivity(%) | ||||
---|---|---|---|---|---|---|---|---|---|
C10 | C12 | C14 | C10—C14 | C16+ | |||||
1 | 60 | 0.5 | 500 | 2.89 | 17 | 57 | 15 | 89 | 11 |
2 | 90 | 0.5 | 500 | 2.00 | 8 | 36 | 33 | 77 | 23 |
3 | 120 | 0.5 | 500 | 1.30 | 0 | 20 | 41 | 61 | 39 |
4 | 60 | 0.1 | 500 | 0.05 | 33 | 22 | 20 | 75 | 25 |
5 | 60 | 0.3 | 500 | 0.80 | 25 | 35 | 25 | 85 | 15 |
6 | 60 | 0.5 | 100 | 0.45 | 20 | 40 | 32 | 92 | 8 |
7 | 60 | 0.5 | 150 | 0.99 | 12 | 44 | 37 | 93 | 7 |
8 | 60 | 0.5 | 250 | 1.34 | 4 | 48 | 30 | 82 | 18 |
Table 2 Results of oligomerization of ethylene using complex/EtAlCl2 as catalyst
Entry | t/min | p/MPa | n(Al)/n(Ni) | 10-6Activity/ [g·(mol Ni·h)-1] | Selectivity(%) | ||||
---|---|---|---|---|---|---|---|---|---|
C10 | C12 | C14 | C10—C14 | C16+ | |||||
1 | 60 | 0.5 | 500 | 2.89 | 17 | 57 | 15 | 89 | 11 |
2 | 90 | 0.5 | 500 | 2.00 | 8 | 36 | 33 | 77 | 23 |
3 | 120 | 0.5 | 500 | 1.30 | 0 | 20 | 41 | 61 | 39 |
4 | 60 | 0.1 | 500 | 0.05 | 33 | 22 | 20 | 75 | 25 |
5 | 60 | 0.3 | 500 | 0.80 | 25 | 35 | 25 | 85 | 15 |
6 | 60 | 0.5 | 100 | 0.45 | 20 | 40 | 32 | 92 | 8 |
7 | 60 | 0.5 | 150 | 0.99 | 12 | 44 | 37 | 93 | 7 |
8 | 60 | 0.5 | 250 | 1.34 | 4 | 48 | 30 | 82 | 18 |
Entry | n(Al)/n(Ni) | 10-5 Activity/ [g·(mol Ni·h)-1] | Selectivity(%) | ||
---|---|---|---|---|---|
C15 | C20 | C25+ | |||
1 | 100 | 2.01 | 3.0 | 24.3 | 72.7 |
2 | 150 | 2.63 | 1.1 | 44.3 | 54.6 |
3 | 250 | 2.35 | 1.2 | 48.5 | 50.3 |
4 | 300 | 2.47 | 4.5 | 70.5 | 25.0 |
5 | 350 | 2.11 | 1.4 | 63.1 | 35.5 |
6 | 500 | 2.06 | 2.4 | 65.2 | 32.4 |
Table 3 Results of oligomerization of 1-pentene using complex/EtAlCl2 as catalyst
Entry | n(Al)/n(Ni) | 10-5 Activity/ [g·(mol Ni·h)-1] | Selectivity(%) | ||
---|---|---|---|---|---|
C15 | C20 | C25+ | |||
1 | 100 | 2.01 | 3.0 | 24.3 | 72.7 |
2 | 150 | 2.63 | 1.1 | 44.3 | 54.6 |
3 | 250 | 2.35 | 1.2 | 48.5 | 50.3 |
4 | 300 | 2.47 | 4.5 | 70.5 | 25.0 |
5 | 350 | 2.11 | 1.4 | 63.1 | 35.5 |
6 | 500 | 2.06 | 2.4 | 65.2 | 32.4 |
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