Hydrodeoxygenation of Guaiacol over Nickel-based Catalyst Supported on Mixed Oxides

doi:10.7503/cjcu20130651

Abstract

Abstract:

Using bimetal mixed oxides Al₂O₃-SiO₂, Al₂O₃-TiO₂, TiO₂-SiO₂and TiO₂-ZrO₂ as supports, nickel catalysts were tested through hydrodeoxygenation(HDO) reaction of guaiacol and characterized by Brunauer-Emmett-Teller(BET), X-ray diffraction(XRD), NH₃ temperature programme desorption(NH₃-TPD) and H₂ temperature programme reduction(H₂-TPR) techniques. The effects of support, solvent, reaction temperature and pressure on conversion of guaiacol and selectivity of different products were studied. The resistance of coke, recyclability of catalyst and the reaction mechanism for guaiacol hydrodeoxygenation were also discussed. The results show that the activities of Ni/TiO₂-ZrO₂ are obviously better than the others under the same reaction conditions. The conversion of guaiacol over Ni/TiO₂-ZrO₂ catalyst is 100% and the selectivity for cyclohexane is as high as 86.4% under the optimization condition of 300 ℃ and the initial H₂ pressure of 4 MPa in decalin. Moreover, the Ni/TiO₂-ZrO₂catalyst has a better performance of anti-coking than traditional catalysts, about only 3.2%(mass fraction) of residual cokes on the catalyst surface.

Key words: Mixed oxides, Nickel-based catalyst, Guaiacol, Hydrodeoxygenation(HDO)

CLC Number:

O643.3

TrendMD:

KONG Wei, ZHANG Xing-Hua, ZHANG Qi, WANG Tie-Jun, MA Long-Long, CHEN Guan-Yi. Hydrodeoxygenation of Guaiacol over Nickel-based Catalyst Supported on Mixed Oxides[J]. Chem. J. Chinese Universities, 2013, 34(12): 2806.

References

[1] Ma L. L., Wang T. J., Liu Q. Y., Zhang X. H., Ma W. C., Zhang Q., Biotechnol. Advance, 2012, 30(4), 859—873

[2] Yin R. Z., Liu R. H., Mei Y. F., Fei W. T., Sun X. Q., Fuel, 2013, 112, 96—104

[3] Xiu S. N., Shahbazi A., Renew. Sust. Energ. Rev., 2012, 16(7), 4406—4414

[4] Yu Y. X., Zhang X. H., Wang T. J., Xu Y., Ma L. L., Zhang Q., Zhang L. M., Chem. J. Chinese Universities, 2013, 34(9), 2178—2183(于玉肖, 张兴华, 王铁军, 徐莹, 马隆龙, 张琦, 张丽敏. 高等学校化学学报, 2013, 34(9), 2178—2183)

[5] Liu R. H., Huang C. X., Cai J. M., Deng C. J., Trans. Chinese Soc. Agricul. Eng., 2008, 24(3), 308—313(刘荣厚, 黄彩霞, 蔡均猛, 邓春健. 农业工程学报, 2008, 24(3), 308—313)

[6] Senol O. I., Ryymin E. I, Viljava T. R., Krause A. O. I., J. Mol. Catal. A, 2007, 277(1/2), 107—112

[7] Ferrari M., Bosmans M., Maggi R. B., Delmon B., Grange P., Catal. Today, 2001, 65(2-4), 257—264

[8] Sun C. Z., Zhou R. X., Chem. J. Chinese Universities, 2011, 32(7), 1551—1555(孙翠枝, 周仁贤. 高等学校化学学报, 2011, 32(7), 1551—1555)

[9] Xu Y., Wang T. J., Ma L. L., Chen G. Y., Energ. Convers. Manage., 2012, 55, 172—177

[10] Dana P., Petr Z., Martina B., Appl. Catal. A, 2007, 332(1), 56—64

[11] Fisk C. A., Morgan T., Ji Y. Y., Appl. Catal. A, 2009, 358(2), 150—156

[12] Gutierrez A., Kaila R. K., Honkela M. L., Slioot R., Krause A. O. I., Catal. Today, 2009, 147(3/4), 239—246

[13] Bao J. G., Yang Y. Q., Wang W. Y., Jiang X. M., Li Y., J. Fuel Chem. Technol., 2011, 39(1), 59—63(包建国, 杨运泉, 王威燕, 蒋新民, 李娅. 燃料化学学报, 2011, 39(1), 59—63)

[14] Zhang J. X., Luo Z. Y., Dang Q., Wang J., Chen W., Energy Fuels, 2012, 26(5), 2990—2995

[15] Guo X. J., Wang S. R., Wang K. G., Luo Z. Y., Chem. Res. Chinese Universities, 2011, 27(3), 426—430

[16] Maity S. K., Rana M. S., Bej S. K., Ancheyta J. J., Murali D. G., Prasada R. T. S. R., Catal. Lett., 2001, 72(1/2), 115—119

[17] Dai Z. H., Wen X. R., J. Nanjing Normal University, 1999, 22(4), 53-56(戴志晖, 温相如.南京师大学报, 1999, 22(4), 53—56)

[18] Zhang X. H., Wang T. J., Ma L. L., Jang T., Liu Q. Y., Zhang Q., Chinese J. Inorg. Chem., 2010, 26(12), 2182-2188(张兴华, 王铁军, 马隆龙, 江婷, 刘琪英, 章青. 无机化学学报, 2010, 26(12), 2182—2188)

[19] Yao N., Chen J. X., Zhang J. X., Zhang J. Y., Catal. Commun., 2008, 9(7), 1510—1516

[20] Zhu X. L., Lobban L. L., Mallinson R. G., Resasco D. E., J. Catal., 2011, 281(1), 21—29

[21] Popov A., Kondratieva E., Goupil J. M., Mariey L., Bazin P., Gilson J. P., Travert A., Mauge F., J. Phys. Chem. C, 2010, 114(37), 15661—15670

[22] Laurent E., Delmon B., J. Catal., 1994, 146(1), 281—291

[23] Furimsky E., Appl. Catal. A, 2000, 199, 147—190

[24] Ferrari M., Delmon B., Grange P., Carbon, 2002, 40(4), 497—511

[25] Centeno A., Laurent E., Delmon B., J. Catal., 1995, 154, 288—298

[26] Zhang X. H., Wang T. J., Ma L. L., Zhang Q., Jiang T., Bioresour. Technol., 2013, 127, 306—311

[27] Zhao C., Kou Y., Lemonidou A. A., Li X. B., Lercher J. A., Angew. Chem. Int. Ed., 2009, 48(22), 3987—3990

[28] Bykova M. V., Ermakov D. Y., Kaichev V. V., Bulavcheko O. A., Saraev A. A., Lebedev M. Y., Yakovlev V. A., Appl. Catal. B, 2012, 113, 296—307