Synthesis, Structure and Phase Transition of a New Microporous Aluminophosphate [C4N2H14]2+[H2Al3P3O14]2-

doi:10.7503/cjcu20130245

Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (7): 1571.doi: 10.7503/cjcu20130245

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Synthesis, Structure and Phase Transition of a New Microporous Aluminophosphate [C₄N₂H₁₄]²⁺[H₂Al₃P₃O₁₄]^2-

LU Hui-Ying, TONG Xiao-Qiang, YAN Yan, YAN Wen-Fu, YU Ji-Hong, XU Ru-Ren

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Received:2013-03-18 Online:2013-07-10 Published:2013-06-21
Contact: Wenfu Yan E-mail:yanw@jlu.edu.cn

Abstract

Abstract:

In the presence of N-methyl-1,3-diaminopropane, a new microporous aluminophosphate compound [C₄N₂H₁₄]²⁺[H₂Al₃P₃O₁₄]^2-(1) was synthesized under hydrothermal condition. Single-crystal X-ray diffraction structural analysis showed that compound 1 crystallizes in the orthorhombic space group Pbca with a=1.59839(11) nm, b=0.99402(6) nm, c=1.82261(11) nm, V=2.8958(3) nm³. Its framework consists of AlO₅/AlO₆ and PO₄ units forming 10-ring channels along [010] direction, where the templates exists. Compound 1 transformed to AlPO₄-25(ATV) upon calcination at 550℃. It was further characterized by powder X-ray diffraction(PXRD), inductively coupled plasma(ICP) analysis, scanning electron microscopy(SEM), thermal gravimetric(TG) analysis, and elemental analysis.

Key words: Molecular sieve, Aluminophosphate, Open framework, Hydrothermal synthesis

CLC Number:

O611.4

TrendMD:

LU Hui-Ying, TONG Xiao-Qiang, YAN Yan, YAN Wen-Fu, YU Ji-Hong, XU Ru-Ren. Synthesis, Structure and Phase Transition of a New Microporous Aluminophosphate [C₄N₂H₁₄]²⁺[H₂Al₃P₃O₁₄]^2-[J]. Chem. J. Chinese Universities, 2013, 34(7): 1571.

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Synthesis, Structure and Phase Transition of a New Microporous Aluminophosphate [C₄N₂H₁₄]²⁺[H₂Al₃P₃O₁₄]^2-

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