CJCU

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (10): 1144.

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Studies on the Biomimetic Oxidation Catalyzed by the Model Compound of Cytochrome P- 450 ( Ⅷ )——The Influence of Additive Organo-Ligand upon the Catalytic Characteristics of TPPFe( Ⅲ )CI in the Hydroxylation of Cyclohexane by PhIO

Zhu Shenjie, Gui Mingde, Guo Cancheng   

  1. Department of Chemistry, Nankai Unviersity, Tianjin
  • Received:1989-04-21 Online:1990-10-24 Published:1990-10-24

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Abstract: The influence of some additive organo-ligands——pyridine, pyrrole thiophene, furan, imi-dazole and Ph3P upon the catalytic characteristics of TPPFe( Ⅲ )Cl in the hydroxylation of cyclohex-ane by PhIO was reported in this paper.The electronic and steric substituent effects of substituted pyridines on the catalytic activity of TPPFe( Ⅲ )Cl in the above reactions were also studied.

Key words: The influence of organo-ligand, The catalytic characteristics of TPPFe( Ⅲ )Cl, Biomimetic hydroxylation

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