Synthesis, Characterization and the Third-order Nonlinear Optical Properties of a Derivative of {Mo102}-type Porous Inorganic Nano-fullerene

Chem. J. Chinese Universities

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Synthesis, Characterization and the Third-order Nonlinear Optical Properties of a Derivative of {Mo₁₀₂}-type Porous Inorganic Nano-fullerene

ZHOU Yun-Shan^1,2*, HAN Rui-Xue¹, ZHANG Li-Juan¹, LI Yu-Hao¹, ZHANG Li-Hui¹

1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029;
2. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Peking University, Beijing 100871, China

Received:2008-03-07 Revised:1900-01-01 Online:2008-07-10 Published:2008-07-10
Contact: ZHOU Yun-Shan

Abstract

Abstract: A small spherical inorganic fullerene nano-capsule anion of a formula [{(Mo)Mo₅O₂₁(H₂O)₄·SO₄}₁₂{Mo^ⅤO(H₂O)}₃₀]^12- bearing 20 {Mo₆O₆}-type rings/channels built up from 102 Mo atoms and O atoms were synthesized by reacting a highly charged spherical inorganic fullerene nano-capsule anion with the formula [{(Mo^Ⅵ)Mo₅^ⅥO₂₁(H₂O)₆}₁₂{Mo₂^ⅤO₄(SO₄)}₃₀]^72- bearing 20 {Mo₉O₉}-type rings/channels with guanidineacetic acid under acidic conditions at room temperature. The crystal structure of the resulted compound were characterized by X-ray single-crystal diffraction, elemental analysis, TG-DTA analysis and FTIR, UV-Vis, and ESR spectrascopies. It crystallizes in a triclinic system space group P1, a=2.5377(5) nm, b=2.5932(5) nm, c=3.9547(8) nm, α=83.58(3) °, β=86.15(3) °, γ=75.55(3) °, V=25.023(9) nm³. Meanwhile, its third-order nonlinear optical properties were studied using Z-scan technique with 5 ns laser pulse at λ=532 nm. The third-order nonlinear refractive index of the title compound is determined to be γ=-3.29×10^-18 m²/W and the third-order nonlinear susceptibility χ⁽³⁾=-1.04×10^-23 m²·V^-2, showing strong nonlinear self-defocusing refractive effects.

Key words: Inorganic fullerene, Nanostructure, Nonlinear optical property

CLC Number:

O614
O743.53

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ZHOU Yun-Shan^1,2*, HAN Rui-Xue¹, ZHANG Li-Juan¹, LI Yu-Hao¹, ZHANG Li-Hui¹. Synthesis, Characterization and the Third-order Nonlinear Optical Properties of a Derivative of {Mo₁₀₂}-type Porous Inorganic Nano-fullerene[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Characterization and the Third-order Nonlinear Optical Properties of a Derivative of {Mo₁₀₂}-type Porous Inorganic Nano-fullerene

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